• Method for Measuring pH and Alkalinity of High-Pressure Fluid Samples : Evaluation through Artificial Samples

  • Minseok Song·Soohyeon Moon*·Gitak Chae·Jun-Hwan Bang

  • Korea Institute of Geoscience and Mineral Resources (KIGAM), Daejeon 34132, Korea

  • 고압 유체 시료의 pH 및 알칼리도 측정 방법 : 가상 시료를 활용한 실용성 평가

  • 송민석·문수현*·채기탁·방준환

  • 한국지질자원연구원

  • This article is an open access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/by-nc/4.0) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.

References
  • 1. 국무조정실, 2023, 탄녹위 전체회의 보도자료: 2050 탄소중립 달성과 녹색성장 실현’을 위한 국가 전략 및 제1차 국가 기본계획 의결, https://www.opm.go.kr/opm/news/press-release.do?mode =view&articleNo=153151 [Accessed on 27 December 2023]
  •  
  • 2. Ajayi, T., Gomes, J.S., and Bera, A., 2019, A review of CO2 storage in geological formations emphasizing modeling, monitoring and capacity estimation approaches, Pet Sci, 16, 1028-1063, doi:10.1007/s12182-019-0340-8
  •  
  • 3. Alfredson, H.A., Mesfin, K.G., and Wolff-Boenisch, D., 2016, The syringe sampler: An inexpensive alternative borehole sampling technique for CO2-rich fluids during mineral carbon storage, Greenh Gases, 6(2), 167-177, doi:10.1002/ghg.1543
  •  
  • 4. Blackford, J., Bull, J.M., Cevatoglu, M., Connelly, D., Hauton, C., James, R.H., Lichtschlag, A., Stahl, H., Widdicombe, S., and Wright, I.C., 2015, Marine baseline and monitoring strategies for carbon dioxide capture and storage (CCS), Int J Greenh Gas Control, 38, 221-229, doi:10.1016/j.ijggc.2014.10.004
  •  
  • 5. Boreham, C., Underschultz, J., Stalker, L., Kirste, D., Freifeld, B., Jenkins, C., and Ennis-King, J., 2011, Monitoring of CO2 storage in a depleted natural gas reservoir: gas geochemistry from the CO2CRC Otway Project, Australia, Int J Greenh Gas Control, 5(4), 1039-1054.
  •  
  • 6. Cheong, S. and Kim, B.-Y., 2020, Time-lapse seismic monitoring technique for the Otway site, KSMER, 57(1), 35-44, doi: 10.32390/ksmer.2020.57.1.035
  •  
  • 7. Corr Instruments, 2009, High-Temperature High-Pressure pH and Reference Probes Instruction Manual, https://www.salaty. com.my/wp-content/uploads/pdf/CORR INSTRUMENTS/AN/Instructions_high_P&T_pH&Ref_probes_Sep_2009.PDF [Accessed on 27 December 2023]
  •  
  • 8. Drever, J.I., 1997, The Geochemistry of Natural Waters: Surface and Groundwater Environments, 3rd Edition, Prentice Hall, Upper Saddle River, NJ USA, 436pp
  •  
  • 9. Freifeld, B.M., Trautz, R.C., Kharaka, Y.K., Phelps, T.J., Myer, L.R., Hovorka, S.D., and Collins, D.J., 2005, The U‐tube: A novel system for acquiring borehole fluid samples from a deep geologic CO2 sequestration experiment, J Geophys Res Solid Earth, 110, B10, doi:10.1029/2005JB003735
  •  
  • 10. Jo, M., Chae, G.-T., Koh, D.-C., Yu, Y., and Choi, B.-Y., 2009, A Comparison study of alkalinity and total carbon measurements in CO2-rich water, J. Soil Groundwater Environ., 14(3), 1-13
  •  
  • 11. Jones, D.G., Beaubien, S.E., Blackford, J.C., Foekema, E.M., Lions, J., De Vittor, C., West, J.M., Widdicombe, S., Hauton, C., and Queiros, A.M., 2015, Developments since 2005 in understanding potential environmental impacts of CO2 leakage from geological storage, Int J Greenh Gas Control, 40, 350-377, doi:10.1016/j.ijggc.2015.05.032
  •  
  • 12. Kampman, N., Bickle, M.J., Maskell, A., Chapman, H.J., Evans, J.P., Purser, G., Zhou, G., Schaller, M.F., Gattacceca, J.C., Bertier, P., Chen, F., Turchyn, A.V., Assayag, N., Rochelle, C., Ballentine, C.J., and Busch, A., 2014, Drilling and sampling a natural CO2 reservoir: Implications for fluid flow and CO2-fluid–rock reactions during CO2 migration through the overburden, Chem Geol, 369, 51-82, doi:10.1016/j.chemgeo.2013.11. 015
  •  
  • 13. Kharaka, Y.K., Cole, D.R., Thordsen, J.J., Kakouros, E., and Nance, H.S., 2006, Gas–water–rock interactions in sedimentary basins: CO2 sequestration in the Frio Formation, Texas, USA, J Geochem Explor, 89(1-3), 183-186.
  •  
  • 14. Kharaka, Y.K., Thordsen, J.J., Hovorka, S.D., Nance, H.S., Cole, D.R., Phelps, T.J., and Knauss, K.G., 2009, Potential environmental issues of CO2 storage in deep saline aquifers: Geochemical results from the Frio-I Brine Pilot test, Texas, USA, Appl Geochemistry, 24(6), 1106-1112.
  •  
  • 15. Kim, K., Lee, J.-W., Choi, S.-H., Kim, S.-H., Kim, H., Hamm, S.-Y., and Kim, R.-H., 2019, Alkalinity measurement of groundwater using Gran titration method, J. Soil Groundwater Environ., 24(1), 10-16, doi: 10.7857/JSGE.2019.24.1.010
  •  
  • 16. Litynski, J., Rodosta, T., and Brown, B., 2012, Best practices for monitoring, verification, and accounting of CO2 stored in deep geologic formations-2012 update. US DOE/NETL-2012/1568, 136pp
  •  
  • 17. Matter, J.M., Stute, M., Sn©¡björnsdóttir, S.Ó., Oelkers, E.H., Gislason, S.R., Aradottir, E.S., Sigfusson, B., Gunnarsson, I., Sigurdardottir, H., Gunnlaugsson, E., Axelsson, G., Alfredsson, H.A., Wolff-Boenisch, D., Mesfin, K.G., Taya, D.F.R., Hall, J., Dideriksen, K., and Broecker, W.S., 2016, Rapid carbon mineralization for permanent disposal of anthropogenic carbon dioxide emissions, Science, 352(6291), 1312-1314. doi:10.1126/science.aad8132
  •  
  • 18. Mörner, N.-A. and Etiope, G., 2002, Carbon degassing from the lithosphere, Glob Planetary Change, 33(1-2), 185-203, doi:10. 1016/S0921-8181(02)00070-X
  •  
  • 19. Myrttinen, A., Becker, V., Mayer, B., van Geldern, R., and Barth, J.A.C., 2015, Determining in situ pH values of pressurised fluids using stable carbon isotope techniques, Chem Geol, 391,1-6. https://doi.org/10.1016/j.chemgeo.2014.10.015
  •  
  • 20. Raghuraman, B., Gustavson, G., Mullins, O.C., and Rabbito, R., 2006, Spectroscopic pH measurement for high temperatures, pressures and ionic strength, AlChE Journal, 52(9), 3257-3265.
  •  
  • 21. Roberts, J.J., Gilfillan, S.M.V., Stalker, L., and Naylor, M., 2017, Geochemical tracers for monitoring offshore CO2 stores, Int J Greenh Gas Control, 65, 218-234, doi:10.1016/j.ijggc.2017.07. 021
  •  
  • 22. Shitashima, K., Maeda, Y., and Ohsumi, T., 2013, Development of detection and monitoring techniques of CO2 leakage from seafloor in sub-seabed CO2 storage, Appl Geochemistry, 30, 114-124, doi:10.1016/j.apgeochem.2012.08.001
  •  
  • 23. Vesper, D. J., and Edenborn, H. M., 2012, Determination of free CO2 in emergent groundwaters using a commercial beverage carbonation meter. J Hydrol, 438-439, 148-155.
  •  
  • 24. Yang, X., Buscheck, T.A., Mansoor, K., Wang, Z., Gao, K., Huang, L., Appriou, D., and Carroll, S.A., 2019, Assessment of geophysical monitoring methods for detection of brine and CO2 leakage in drinking water aquifers, Int J Green. Gas Control, 90, 102803, doi:10.1016/j.ijggc.2019.102803
  •  
  • 25. Yasemi, S., Khalili, Y., Sanati, A., and Bagheri, M., 2023, Carbon capture and storage: Application in the oil and gas industry, Sustainability, 15(19), 14486, doi:10.3390/su151914486
  •  
  • 26. Zhang, R.H., Zhang, X.T., and Hu, S.M., 2008, Zr/ZrO2 sensors for in situ measurement of pH in high-temperature and-pressure aqueous solutions, Anal Chem, 80(8), 2982-2987.
  •  

This Article

  • 2024; 29(1): 1-9

    Published on Feb 29, 2024

  • 10.7857/JSGE.2024.29.1.001
  • Received on Dec 28, 2023
  • Revised on Jan 14, 2024
  • Accepted on Jan 31, 2024

Correspondence to

  • Soohyeon Moon

  • Korea Institute of Geoscience and Mineral Resources (KIGAM), Daejeon 34132, Korea

  • E-mail: munarang@naver.com