• The Laboratory Column Examination of Stabilization for Agricultural Land Contaminated by Heavy Metals using Sequential Stabilization
  • Park, Dong-Hyeok;Cho, Yun-Chul;Choi, Sang-Il;
  • Department of Environmental Engineering, Kwangwoon University;Graduate School of Green Environment and Energy;Department of Environmental Engineering, Kwangwoon University;
  • 연속 안정화 공법을 이용한 중금속 오염 농경지 토양 안정화 처리를 위한 Column 실험 연구
  • 박동혁;조윤철;최상일;
  • 광운대학교 환경공학과;광운대학교 녹색환경에너지대학원;광운대학교 환경공학과;
Abstract
In order to treat paddy soils contaminated by Pb, Cd, and As near the abandoned mine, $H_2PO_4$ was used for stabilization of Pb ($PO_4$/Pb mole ratio of 2/1). In addition, $CaCO_3$ and $FeSO_4$ were used as stabilizers for treating Cd and As (2% w/w), respectively. Leaching tests were conducted with artificial rain in the column to assess the heavy metal stabilization efficiency. The mass of heavy metals in the effluents passed through the columns were analyzed. The remaining heavy metals in the soils were also analyzed as Korean soil standard method, phytoavailability test and sequential extraction test. Lead in the effluent was not detected when $H_2PO_4$ was used as a stabilizer. This result suggests that $H_2PO_4$ is efficient for Pb stabilization. In addition results of sequential extraction scheme suggest that heavy metals are present as residual forms which is not easily extracted.

Keywords: Mobility;Heavy metal;Phytoavailability;Stabilization;

References
  • 1. 권현호, 심연식, 이진수, 김태혁, 김정아, 윤석호, 남광수, 2007, 광해의 원인과 방지대책, 광해방지기술, 1(1), 5-25.
  •  
  • 2. 김휘중, 양재의, 이재영, 최상일, 전상호, 2003, 폐광산지역 경작지 토양의 중금속 존재형태와 토양오염평가, 8(4), 53-63.
  •  
  • 3. 이은기, 최상일, 2007, 인산염을 이용한 휴.폐광산 주변 중금속 오염토양의 안정화처리에 관한 연구, 한국지하수토양환경학회지, 12(6), 100-106.
  •  
  • 4. 환경부, 2002, 토양오염공정시험법.
  •  
  • 5. 환경부, 2006, 대기 환경연보 부록 08 (산성우).
  •  
  • 6. 환경부, 2007, 오염토양 정화기법 가이드라인.
  •  
  • 7. Hartley, W., Edwards, R., and Lepp, N.W., 2004, Arsenic and heavy metal mobility in iron oxide-amended contaminated sils as evaluated by short- and long-term leaching tests, Environmental Pollution, 131, 495-504.
  •  
  • 8. Kumpiene, J., Lagerkvist., A., and Maurice, C., 2007, Stabilization of As, Cr, Cu, Pb and Zn in soil using amendments- A review, Waste Management, 28(1), 215-225.
  •  
  • 9. Liu, R. and Zhao, D., 2007, Reducing leachability and bioaccessibility of lead in soils using a new class of stabilized iron phosphate nanoparticles, Water Research, 41, 2491-2502.
  •  
  • 10. Ma, Q.Y., Traina, S.J., Logan, T.J., and Ryan, J.A., 1993, In Situ Lead Immobilization by Apatite Environ. Sci. Technol., 27, 1803-1810.
  •  
  • 11. Spuller, C., Weigand, H., and Marb, C., 2007, Trace metal stabilisation in a shooting range soil: Mobility and phytotoxicity, Journal of Hazardous Materials, 141, 378-387.
  •  
  • 12. Tessier, A., Campbell, P.G.C., and Bisson, M., 1979. Sequential extraction procedure for the speciation of particulate trace metal. Anal. Chem., 51, 844-851.
  •  
  • 13. Thomas, G.W., 1982, Exchangeable cations. In: Page, A.L., Miller, R.H., Keeney, D.R. (Eds.), Methods of Soil Analysis, Part II: Chemical and Microbiological Properties. American Society of Agronomy, Madison, WI, p. 159-165.
  •  

This Article

  • 2010; 15(4): 39-45

    Published on Aug 31, 2010

  • Received on May 13, 2010
  • Accepted on Jul 6, 2010