• Removal of Arsenic in Waste Water using Pachymeniopsis sp. and Its Application to Soil Washing Process
  • Jung, Hyun-Gyu;Kim, Yu-Beom;Choi, Sang-Il;Kim, Sun-Gu;Kim, Hee-Jung;
  • Ecobio Co.,Ltd;Ecobio Co.,Ltd;Department of Environmental Engineering, Kwangwoon University;Institute for Occup. & Envi. Health, Korea University;Department of Environmental Science, Kangwon National University;
  • Pachymeniopsis sp.의 폐수 내 가용성 비소 제거 가능성 평가 및 토양세척공법에의 적용
  • 정현규;김유범;최상일;김선구;김휘중;
  • (주)에코바이오;(주)에코바이오;광운대학교 사회환경시스템공학과;고려대학교 환경의학연구소;강원대학교 환경연구소;
Abstract
In this report, we provide experimental evidence that heavy metal ions could be removed using Pachymeniopsis sp., particularly soluble arsenic in leachate from soil contaminated by arsenic. We performed pilot scale of soil washing process based on our results. The adsorption of arsenic by Pachymeniopsis sp. indicated that it could be described with the Langmuir Model and the maximum adsorption capacity increased with decreasing pH (pH 3: 102.48 mg/g, pH 5: 98.32 mg/g, pH 7: 57.70 mg/g, pH 9: 43.34 mg/g) and increasing temperature (10$^{\circ}C$ : 60.38 mg/g, 20$^{\circ}C$ : 76.39 mg/g, 30$^{\circ}C$ : 112.12 mg/g). Our results revealed that soluble arsenic in leachate was removed from 24.03 mg/L to 0.6 ${\pm}$ 0.1 mg/L by Pachymeniopsis sp. for 48hours on pilot scale of soil washing process.

Keywords: Arsenic;Pachymeniopsis sp.;Soil washing;Biosorbent;Langmuir model;

References
  • 1. 김명진, 2002, 지질 환경재해 및 복원기술: 중금속 오염토양의 정화 및 복원, 한국자원공학회.한국지하수토양환경학회.대한광업진흥공사 공동 학술 심포지엄 논문집, 대한광업진흥공사, 서울, p. 117-141.
  •  
  • 2. 김용무, 이해익, 2003, 해조류로부터 6가 크롬 흡착 제거제의 선발, 강원대학교 농업과학연구소 논문집, 14, 97-103.
  •  
  • 3. 서근학, 안갑환, 공인수, 1999, 해조류 Sargassum sagamlanum을 이용한 Pb흡착 및 탈착, 한국생물공학회지, 14(5), 611-615.
  •  
  • 4. 유경열, 2003, Zero-Valent Iron(ZVI)에 의한 As의 불용화기작, 강원대학교 농학석사논문, p. 25-27.
  •  
  • 5. 유경열, 옥용식, 양재의, 2006, 수용액 중 영가 철의 비소흡착 및 반응기작 구명, 한국토양비료학회지, 39(3), 157-162.
  •  
  • 6. Alam, M.G.M., Tokunaga, S., and Aekawa, T.M., 2001, Extraction of arsenic in a synthetic arsenic-contaminated soil using phosphate. Chemospere, 43, 1035-1041.
  •  
  • 7. Ehrlich, H.L. and Brierley, C., 1990, Microbial mineral recovery, McGraw-Hill Publishing Com, p. 27-29.
  •  
  • 8. Holan, Z.R., Volesky, B., and Prasetyo, I., 1993, Biosorption od cadmium by biomass of marine algae, Biotech. Bioeng, 41, 819-825.
  •  
  • 9. Kiefer, E., Sigg, L., and Schosseler, P., 1997, Chemical and spectroscopic chracterization of algae surfaces, Environ. Sci. & Technol, 31, 759-764.
  •  
  • 10. Kuyucak, N. and Volesky, B., 1989, Accumulation of cobalt by marine algae, Biotechnology and Bioengineering, 33, 809-814.
  •  
  • 11. Sparks, D.L., 1995, Environmental soil chemistry, Academics Press, USA, p. 99-185.
  •  
  • 12. Suh, K.H., Ahn, K.H., and Cho, M.C., 1998, biosorption of Pb and Cu by marine algae, Korean J. Biotechnol. Bioeng., 13, 444-448.
  •  
  • 13. Volesky, B., 1990, Biosorption of heavy metals, CRC Press, p. 132-138.
  •  

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