• Evaluation of Leaching Potential of Heavy Metals from Bottom Ashes Generated in Coal-fired Power Plants in Korea
  • Park, Dongwon;Choi, Hanna;Woo, Nam C.;Kim, Heejoung;Chung, David;
  • Department of Earth System Science, Yonsei University;Department of Earth System Science, Yonsei University;Department of Earth System Science, Yonsei University;Institute of Environmental Research at Kangwon National University;Resource Recirculation Research Division, National Institute of Environmental Research;
  • 국내 석탄 화력발전소 배출 바닥재의 중금속 용출 가능성 평가
  • 박동원;최한나;우남칠;김휘중;정다위;
  • 연세대학교 지구시스템과학과;연세대학교 지구시스템과학과;연세대학교 지구시스템과학과;강원대학교 환경연구소;국립환경과학원 자원순환연구과;
Abstract
This study was objected to evaluate the potential impact on the groundwater environment of the coal bottom ash used as fill materials on the land surface. From four coal-fired power plants, bottom-ashes were collected and analyzed through sequential extraction and column leaching tests following the meteoric water mobility procedure. The column tests shown leaching heavy metals including Pb, As, B, Cu, Zn, Mn, Ni, Ba, Sr, Sb, V, Cr, Mo, and Hg. The relatively high concentrations of B, Sr, Ba, and V in leachate were attributed to both the higher concentrations in the bottom ash and the relatively higher portion of leachable state, sorbed state, of metals. Bottom-ash samples from the D-plant only show high leaching potential of sulfate ($SO_4$), probably originated from the coal-combustion process, called the Fluidized Bed Combustion. Consequently, to manage recycling bottom ashes as fill materials, an evaluation system should be implemented to test the leaching potentials of metals from the ashes considering the absolute amount of metals and their state of existence in ashes, and the coal-combustion process.

Keywords: Coal bottom ash;Leaching potential;Sequential Extraction;Column leaching test;

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This Article

  • 2013; 18(7): 32-40

    Published on Dec 30, 2013

  • 10.7857/JSGE.2013.18.7.032
  • Received on Aug 28, 2013
  • Revised on Dec 16, 2013
  • Accepted on Dec 17, 2013