Effect of Differences between Korean Ministry of Environment Standard and ISO Standard on Determination of Petroleum Hydrocarbon Content in Soil

doi:10.7857/JSGE.2012.17.4.063

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2012 Vol.17, Issue 4 Preview Page Next Page

Effect of Differences between Korean Ministry of Environment Standard and ISO Standard on Determination of Petroleum Hydrocarbon Content in Soil 토양오염공정시험기준과 국제표준간의 분석방법 차이가 유류 정량에 미치는 영향: 정인호;이군택;이원석;김용훈;김보현;김지인;김보경;
Jung, In-Ho;Lee, Goon-Taek;Lee, Won-Seok;Kim, Yong-Hoon;Kim, Bo-Hyun;Kim, Ji-In;Kim, Bo-Kyong;

31 August 2012. pp. 63 ~ 72

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Abstract

The main objective of this study is to assess the compatibility between Korean ministry of environment (KME) standard and ISO (KS I ISO) standard for the determination of BTEX and TPH content in soil. We carried out comparison analysis for both methods using CRM and matrix spiked samples. In case of GC-MS analysis for BTEX, we got statistically (significance level: 0.05) the same results from KME standard (ES 07600.1) and ISO standard (KS I ISO 15009). However, it showed statistically (significance level: 0.05) different results when TPH was analyzed by KME standard (ES 07552.1) and ISO standard (KS I ISO 16703). To clarify the reason why both methods produced different results for TPH content, we also did some additional experiments in terms of differences in extraction, clean-up and target hydrocarbon range. Extraction with polar and non-polar compounds mixed solvent (acetone+n-heptane) of KS I ISO 16703 showed higher extraction efficiency than with only non polar solvent (dichloromethane) extraction of ES 07552.1 by about 9%. While column type clean-up of KS I ISO 16703 showed the reduction in TPH content between before and after clean-up, batch type of clean-up of ES 07552.1 did not show any changes in TPH content through clean-up process. The target hydrocarbon range of ES 07552.1 and KS I ISO 16703 is $C_8{\sim}C_{40}$ and $C_{10}{\sim}C_{40}$, respectively. From this point of view, kerosene and JP-8 contaminated soil showed higher RPD (relative producibility deviation) values between results by both method than that of lubricant or diesel contaminated soil. The higher content of hydrocarbon ($C_8{\sim}C_{10}$) in kerosene and JP-8 played an important role in increasing RPD values in addition to the effects caused by different solvents and clean-up method. Consequently, it was concluded that both methods (ES 07552.1 and KS I ISO 16703) were not compatible.

Keywords

BTEX;TPH;Analytical method;Compatibility;ISO Standard;

References

국가표준인증종합정보센터, 2012, http://www.standard.go.kr
국립농업과학원, 2012, http://soil.rda.go.kr/webgis/webgis.jsp
김태승, 이정희, 김연호, 황승율, 장준영, 박완모, 조희정, 김창희, 신선경, 김삼권, 나진균, 2002, 미규제 미량유기오염물질 분석기법 개발에 관한 연구(IV), 국립환경연구원보, 24, 43-55.
류순호, 2000, 토양사전, 서울대학교출판부, p. 473-477.
박동준, 강인선, 2009, WTO/TBT 협정에 따른 기술규제 동향과 대응방안:기술표준에 의한 생산성 제고 관점, 생산성논집, 23(4), 379-339.
법제처, 2012, 환경분야시험검사 등에 관한 법률(법률 제11266호).
이군택, 2004, 적용된 분석방법 차이에 따른 토양 중 풍화 경유 함량 비교, 지하수토양환경, 9(3), 33-37.
전홍석, 이재준, 고광백, 1998, 환경통계학, 동화기술, p. 163-175.
환경부, 2009, 토양오염공정시험기준(환경부고시 제2009-255호).
Cole, G.M., 1994, Assessment and Remediation of Petroleum Contaminated Sites, CRC Press, Boca Raton, FL, p. 65.
Florida, D.E.P., 1995, Method for determination of petroleum range organics (method #FL-PRO).
ISO, 2012, http://www.iso.org/iso/home/standards_development/list_of_iso_technical_committees.htm
Koch, M., Liebich, A., Win, T., and Nehls, I., 2005, Certified reference materials for the determinatin of mineral oil hydrocarbons in water, soil and waste, BAM, Germany.
KS I ISO 15009, 2004, 토양의 질 - 가스크로마토그래프를 이용한 휘발성 방향족 탄화수소, 나프탈렌, 휘발성 할로겐 족 탄화수소 화합물 정량 - 열 탈착 퍼지 트랩.
KS I ISO 16703, 2005, 토양의 질-가스크로마토그래프를 이용한 C10-C40 범위의 탄화수소 함량 측정.
prEN 14039, 2000, Characterization of waste: Determination of hydrocarbon content in the range of $C_{10}$ to $C_{40}$ by gas chromatography.
Sui, H., Xingang, L, and Du, Y., 2011, Factors controlling complex solvent extraction of petroleum hydrocarbons contaminated soil, Proceedings of the American Institute of Chemical Engineers Annual Meeting, AIChE, Minneapolis, USA.

Information

Publisher :The Korean Society of Soil and Groundwater Environment
Publisher(Ko) :한국지하수토양환경학회
Journal Title :Journal of Soil and Groundwater Environment
Journal Title(Ko) :지하수토양환경
Volume : 17
No :4
Pages :63 ~ 72
DOI :https://doi.org/10.7857/JSGE.2012.17.4.063

[1] 국가표준인증종합정보센터, 2012, http://www.standard.go.kr

[2] 국립농업과학원, 2012, http://soil.rda.go.kr/webgis/webgis.jsp

[3] 김태승, 이정희, 김연호, 황승율, 장준영, 박완모, 조희정, 김창희, 신선경, 김삼권, 나진균, 2002, 미규제 미량유기오염물질 분석기법 개발에 관한 연구(IV), 국립환경연구원보, 24, 43-55.

[4] 류순호, 2000, 토양사전, 서울대학교출판부, p. 473-477.

[5] 박동준, 강인선, 2009, WTO/TBT 협정에 따른 기술규제 동향과 대응방안:기술표준에 의한 생산성 제고 관점, 생산성논집, 23(4), 379-339.

[6] 법제처, 2012, 환경분야시험검사 등에 관한 법률(법률 제11266호).

[7] 이군택, 2004, 적용된 분석방법 차이에 따른 토양 중 풍화 경유 함량 비교, 지하수토양환경, 9(3), 33-37.

[8] 전홍석, 이재준, 고광백, 1998, 환경통계학, 동화기술, p. 163-175.

[9] 환경부, 2009, 토양오염공정시험기준(환경부고시 제2009-255호).

[10] Cole, G.M., 1994, Assessment and Remediation of Petroleum Contaminated Sites, CRC Press, Boca Raton, FL, p. 65.

[11] Florida, D.E.P., 1995, Method for determination of petroleum range organics (method #FL-PRO).

[12] ISO, 2012, http://www.iso.org/iso/home/standards_development/list_of_iso_technical_committees.htm

[13] Koch, M., Liebich, A., Win, T., and Nehls, I., 2005, Certified reference materials for the determinatin of mineral oil hydrocarbons in water, soil and waste, BAM, Germany.

[14] KS I ISO 15009, 2004, 토양의 질 - 가스크로마토그래프를 이용한 휘발성 방향족 탄화수소, 나프탈렌, 휘발성 할로겐 족 탄화수소 화합물 정량 - 열 탈착 퍼지 트랩.

[15] KS I ISO 16703, 2005, 토양의 질-가스크로마토그래프를 이용한 C10-C40 범위의 탄화수소 함량 측정.

[16] prEN 14039, 2000, Characterization of waste: Determination of hydrocarbon content in the range of $C_{10}$ to $C_{40}$ by gas chromatography.

[17] Sui, H., Xingang, L, and Du, Y., 2011, Factors controlling complex solvent extraction of petroleum hydrocarbons contaminated soil, Proceedings of the American Institute of Chemical Engineers Annual Meeting, AIChE, Minneapolis, USA.

Journal of Soil and Groundwater Environment ISSN:1598-6438(Print) 2287-8831(Online) 지하수토양환경

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