Production Method of Biochar-bead from Biochar Powder and Its Application for the Removal of Heavy Metal

doi:10.7857/JSGE.2015.20.6.127

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2015 Vol.20, Issue 6 Preview Page Next Page

Production Method of Biochar-bead from Biochar Powder and Its Application for the Removal of Heavy Metal 분말 바이오-숯으로부터 중금속 오염수 처리용 바이오-숯 비드 제조 및 적용: 최유림;노훈;이규범;신복수;주완호;김남국;김진홍;양재규;;조성희;장윤영;
Choi, Yu-Lim;Roh, Hoon;Lee, Kyu-Beom;Shin, Bok-Su;Joo, Wan-Ho;Kim, Nam-Kook;Kim, Jin-Hong;Yang, Jae-Kyu;Reddy Koduru, Janardhan;Cho, Sung-Heui;Chang, Yoon-Young;

30 November 2015. pp. 127 ~ 132

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Abstract

In this study, biochar-bead, prepared from biochar powder derived from woody biomass, was used for removal cadmium ion in aqueous solution. Various mixing ratios of alginate solution and biochar powder were used for the production of round shape biochar-bead. An optimum mixing ratio was selected as 1.5% alginate solution and 20 wt% biochar. The produced biochar-bead was characterized by SEM, FT-IR, and XRD analyses. The adsorption capacity of Cd(II) by biochar-bead was found to be 9.72 mg/g which was higher than that by GAC and PAC. According to this study, round shape biochar-bead is expected to be used as a media for reactive barrier or water filtration.

Keywords

Adsorption;Biochar;Cadmium;Pyrolysis;

References

Aristidis, N.A. and Kallirroy-Ioanna, G.I., 2010, Development of a sequential injection dispersive liquid-iquid microextraction system for electrothermal atomic absorption spectrometry by using a hydrophobic sorbent material: Determination of lead and cadmium in natural waters, Anal. Chim. Acta, 668, 35-40.10.1016/j.aca.2009.10.063
Cao, X., Ma, L., Gao B., and Willie H., 2009, Dairy-Manure Derived Biochar Effectively Sorbs Lead and Atrazine, Environ. Sci. Technol, 43, 3285-3291.10.1021/es803092k
Dinesh, M., Charles, U.P.Jr, Mark. B., Fran, S., Ben, Y., Javeed, M., Philip, H.S., Maria, F.A.-F., Vicente, G.-S., and Henry, G., 2007, Sorption of arsenic, cadmium, and lead by chars produced from fast pyrolysis of wood and bark during bio-oil production, J. Colloid Interface Sci., 310, 57-73.10.1016/j.jcis.2007.01.020
Ednilton, M.G., Adriana, da S., and Valfredo, A.L., 2006, Preconcentration system for cadmium and lead determination in environmental samples using polyurethane foam/Me-BTANC, J. Hazard. Mater., B136, 757-762.
Fbio, K., Fbio, F.S., Rbia, K., Alexandre, L.S., and Pedro, V.O., 2008, Biomonitoring method for the simultaneous determination of cadmium and lead in whole blood by electrothermal atomic absorption spectrometry for assessment of environmental exposure, Talanta, 75, 246-252.10.1016/j.talanta.2007.11.003
Ho, Y.S. and Mckay, G., 1998, Sorption of dye from aqueous solution by peat, Chem. Eng. J., 70, 115-124.10.1016/S0923-0467(98)00076-1
Huang, P. and Fuerstenau, D.W., 2001, The effect of the adsorption of lead and cadmium ions on the interfacial behavior of quartz and talc, Colloids and Surfaces A: Physicochem. Eng. Asp., 177, 147-156.10.1016/S0927-7757(00)00667-1
Kalyan Yakkala, Yu, M.R., Roh, H., Yang, J.K., and Chang, Y.Y., 2013, Buffalo weed (Ambrosia trifida L. var. trifida) biochar for cadmium (II) and lead (II) adsorption in single and mixed system, Desalin. Water Treat., 51, 7732-7745.10.1080/19443994.2013.792546
Kim, J.D., Park, J.S., Doh, I.H., and Bae, J.K., 2008, Technologies and Strategies for woody biomass waste-to-energy, J. of KORRA, 16-2, 97-111.
Laird, D.A., Brown, R.C, Amonette, J.E., and Lehmann. J., 2009, Review of the pyrolysis platform for coproducing bio-oil and biochar, Biofuel. Bioprod. Bior, 3, 547-562.10.1002/bbb.169
Lehmann, J. and Joseph, S., 2009, Biochar for environmental management: science and technology. London: Earthscan, Ltd.
Lu, H., Zhang, W., Yang, Y., Huang, X., and Wang, S.R.Q., 2012, Relative distribution of Pb²⁺ sorption mechanisms by sludge-derived biochar, Water Res., 46, 854-862.10.1016/j.watres.2011.11.058
Luke, B. and Marta, M., 2011, The immobilisation and retention of soluble arsenic, cadmium and zinc by biochar, Environ. Pollut., 159, 474-480.10.1016/j.envpol.2010.10.016
Ministry of Agriculture and Forestry, 2000, Utilization of Discarded Tree Debris for Commercial Production of Activated Carbon.
Minori, U., Isabel, M.L., Thomas, K.K., Chang, S., Lynda, H.W., and James E.R., 2010, Immobilization of Heavy Metal Ions (CuII, CdII, NiII, and PbII) by Broiler Litter-Derived Biochars in Water and Soil, J. Agric. Food Chem., 58, 5538-5544.10.1021/jf9044217
National Institute of Forest Science of Korea, 2011, Development of new oil feild using wood, Forestry information, 88-92.
Shahryar, A., Kobra, K., and Freshteh, A., 2011, Simultaneous determination of ultra trace amounts of lead and cadmium in food samples by adsorptive stripping voltammetry, Food Chem., 128, 254-257.10.1016/j.foodchem.2011.02.067
Zheng, W., Guo, M., Chow, T., Bennett, D.N., and Rajagopalan, N., 2010, Sorption properties of green waste biochar for two triazine pesticides, J. Hazard. Mater., 181, 121-126.10.1016/j.jhazmat.2010.04.103

Information

Publisher :The Korean Society of Soil and Groundwater Environment
Publisher(Ko) :한국지하수토양환경학회
Journal Title :Journal of Soil and Groundwater Environment
Journal Title(Ko) :지하수토양환경
Volume : 20
No :6
Pages :127 ~ 132
DOI :https://doi.org/10.7857/JSGE.2015.20.6.127

[1] Aristidis, N.A. and Kallirroy-Ioanna, G.I., 2010, Development of a sequential injection dispersive liquid-iquid microextraction system for electrothermal atomic absorption spectrometry by using a hydrophobic sorbent material: Determination of lead and cadmium in natural waters, Anal. Chim. Acta, 668, 35-40.10.1016/j.aca.2009.10.063

[2] Cao, X., Ma, L., Gao B., and Willie H., 2009, Dairy-Manure Derived Biochar Effectively Sorbs Lead and Atrazine, Environ. Sci. Technol, 43, 3285-3291.10.1021/es803092k

[3] Dinesh, M., Charles, U.P.Jr, Mark. B., Fran, S., Ben, Y., Javeed, M., Philip, H.S., Maria, F.A.-F., Vicente, G.-S., and Henry, G., 2007, Sorption of arsenic, cadmium, and lead by chars produced from fast pyrolysis of wood and bark during bio-oil production, J. Colloid Interface Sci., 310, 57-73.10.1016/j.jcis.2007.01.020

[4] Ednilton, M.G., Adriana, da S., and Valfredo, A.L., 2006, Preconcentration system for cadmium and lead determination in environmental samples using polyurethane foam/Me-BTANC, J. Hazard. Mater., B136, 757-762.

[5] Fbio, K., Fbio, F.S., Rbia, K., Alexandre, L.S., and Pedro, V.O., 2008, Biomonitoring method for the simultaneous determination of cadmium and lead in whole blood by electrothermal atomic absorption spectrometry for assessment of environmental exposure, Talanta, 75, 246-252.10.1016/j.talanta.2007.11.003

[6] Ho, Y.S. and Mckay, G., 1998, Sorption of dye from aqueous solution by peat, Chem. Eng. J., 70, 115-124.10.1016/S0923-0467(98)00076-1

[7] Huang, P. and Fuerstenau, D.W., 2001, The effect of the adsorption of lead and cadmium ions on the interfacial behavior of quartz and talc, Colloids and Surfaces A: Physicochem. Eng. Asp., 177, 147-156.10.1016/S0927-7757(00)00667-1

[8] Kalyan Yakkala, Yu, M.R., Roh, H., Yang, J.K., and Chang, Y.Y., 2013, Buffalo weed (Ambrosia trifida L. var. trifida) biochar for cadmium (II) and lead (II) adsorption in single and mixed system, Desalin. Water Treat., 51, 7732-7745.10.1080/19443994.2013.792546

[9] Kim, J.D., Park, J.S., Doh, I.H., and Bae, J.K., 2008, Technologies and Strategies for woody biomass waste-to-energy, J. of KORRA, 16-2, 97-111.

[10] Laird, D.A., Brown, R.C, Amonette, J.E., and Lehmann. J., 2009, Review of the pyrolysis platform for coproducing bio-oil and biochar, Biofuel. Bioprod. Bior, 3, 547-562.10.1002/bbb.169

[11] Lehmann, J. and Joseph, S., 2009, Biochar for environmental management: science and technology. London: Earthscan, Ltd.

[12] Lu, H., Zhang, W., Yang, Y., Huang, X., and Wang, S.R.Q., 2012, Relative distribution of Pb²⁺ sorption mechanisms by sludge-derived biochar, Water Res., 46, 854-862.10.1016/j.watres.2011.11.058

[13] Luke, B. and Marta, M., 2011, The immobilisation and retention of soluble arsenic, cadmium and zinc by biochar, Environ. Pollut., 159, 474-480.10.1016/j.envpol.2010.10.016

[14] Ministry of Agriculture and Forestry, 2000, Utilization of Discarded Tree Debris for Commercial Production of Activated Carbon.

[15] Minori, U., Isabel, M.L., Thomas, K.K., Chang, S., Lynda, H.W., and James E.R., 2010, Immobilization of Heavy Metal Ions (CuII, CdII, NiII, and PbII) by Broiler Litter-Derived Biochars in Water and Soil, J. Agric. Food Chem., 58, 5538-5544.10.1021/jf9044217

[16] National Institute of Forest Science of Korea, 2011, Development of new oil feild using wood, Forestry information, 88-92.

[17] Shahryar, A., Kobra, K., and Freshteh, A., 2011, Simultaneous determination of ultra trace amounts of lead and cadmium in food samples by adsorptive stripping voltammetry, Food Chem., 128, 254-257.10.1016/j.foodchem.2011.02.067

[18] Zheng, W., Guo, M., Chow, T., Bennett, D.N., and Rajagopalan, N., 2010, Sorption properties of green waste biochar for two triazine pesticides, J. Hazard. Mater., 181, 121-126.10.1016/j.jhazmat.2010.04.103

Journal of Soil and Groundwater Environment ISSN:1598-6438(Print) 2287-8831(Online) 지하수토양환경

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