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2022 Vol.27, Issue 6 Preview Page
Single and Binary Competitive Sorption of Phenanthrene and Pyrene in Natural and Synthetic Sorbents
Md Abdullah Al Masud1
,
Won Sik Shin1*
1School of Architecture, Civil, Environmental and Energy Engineering, Kyungpook National University, Daegu 41566, Republic of Korea
*Corresponding Author
31 December 2022. pp. 11-21
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Abstract

Sorption of phenanthrene (PHE) and pyrene (PYR) in several sorbents, i.e., natural soil, BionSoil®, Pahokee peat, vermicompost and Devonian Ohio Shale and a surfactant (hexadecyltrimethyl ammonium chloride)-modified montmorillonite (HDTMA-M) were investigated. Pyrene exhibited higher sorption tendency than phenanthrene, as predicted by its higher octanol to water partition coefficient (Kow). Several sorption models: linear, Freundlich, solubility-normalized Freundlich model, and Polanyi-Manes model (PMM) were used to analyze sorption isotherms. Linear isotherms were observed for natural soil, BionSoil®, Pahokee peat, vermicompost, while nonlinear Freundlich isotherms fitted for Ohio shale and HDTMA-M. The relationship between sorption model parameters, organic carbon content (foc), and elemental C/N ratio was studied. In the binary competitive sorption of phenanthrene and pyrene in natural soil, competition between the solutes caused reduction in the sorption of each solute compared with that in the single-solute system. The ideal adsorbed solution theory (IAST) coupled with the single-solute Freundlich model was not successful in describing the binary competitive sorption equilibria. This was due to the inherent nature of linear sorption of phenanthrene and pyrene in natural soil. The result indicates that the applicability of IAST for the prediction of binary competitive sorption is limited when the sorption isotherms are inherently linear.

Keywords
Competition
Phenanthrene
Pyrene
Sorption
Sorbent
References
1

Akinpelu, A.A., Ali, M.E., Johan, M.R., Saidur, R., Qurban, M.A., and Saleh, T.A., 2019, Polycyclic aromatic hydrocarbons extraction and removal from wastewater by carbon nanotubes: A review of the current technologies, challenges and prospects, Process Saf. Environ. Prot., 122, 68-82. https://doi.org/10.1016/j.psep.2018.11.006

10.1016/j.psep.2018.11.006
2

Al-Masud, M.A., Kim, D.G., and Shin, W.S., 2022a, Highly efficient degradation of phenolic compounds by Fe(II)-activated dual oxidant (persulfate/calcium peroxide) system, Chemosphere, 299, 134392. https://doi.org/10.1016/j.chemosphere.2022.134392

10.1016/j.chemosphere.2022.134392
3

Al-Masud, M.A., Shin, W.S., and Kim, D.G., 2023, Degradation of phenol by ball-milled activated carbon (ACBM) activated dual oxidant (persulfate/calcium peroxide) system: Effect of preadsorption and sequential injection, Chemosphere, 312, 137120. https://doi.org/10.1016/j.chemosphere.2022.137120

10.1016/j.chemosphere.2022.137120
4

Barriuso, E., Baer, U., and Calvet, R., 1992, Dissolved organicmatter and adsorption-desorption of dimefuron, atrazine, and carbetamide by soils, J. Environ. Qual., 21(3), 359-367.

10.2134/jeq1992.00472425002100030009x
5

Billemont, P., Heymans, N., Normand, P., and De Weireld, G., 2017, IAST predictions vs co-adsorption measurements for CO2 capture and separation on MIL-100 (Fe), Adsorption, 23, 225-237. https://doi.org/10.1007/s10450-016-9825-6

10.1007/s10450-016-9825-6
6

Bui, T.X. and Choi, H., 2010, Comment on adsorption and desorption of oxytetracycline and carbamazepine by multiwalled carbon nanotubes, Environ. Sci. Technol., 44(12), 4828. https://doi.org/10.1021/es100684f

10.1021/es100684f
7

Chen, Xian, Liang, J., Bao, L., Gu, X., Zha, S., and Chen, X., 2022, Competitive and cooperative sorption between triclosan and methyl triclosan on microplastics and soil, Environ. Res., 212, 113548. https://doi.org/10.1016/j.envres.2022.113548

10.1016/j.envres.2022.113548
8

Choi, J. and Shin, W.S., 2020, Removal of salicylic and ibuprofen by hexadecyltrimethylammonium-modified montmorillonite and zeolite, Minerals, 10(10), 898. https://doi.org/10.3390/min10100898

10.3390/min10100898
9

Kim, J.-H., Shin, W.S., Song, D.-I., and Choi, S.J., 2005, Multistep competitive sorption and desorption of chlorophenols in surfactant modified montmorillonite, Water. Air. Soil Pollut., 166, 367-380. https://doi.org/10.1007/s11270-005-6329-5

10.1007/s11270-005-6329-5
10

Kim, Y.S., Song, D.I., Jeon, Y.W., and Choi, S.J., 1996, Adsorption of organic phenols onto hexadecyltrimethylammoniumtreated montmorillonite, Sep. Sci. Technol., 31(20), 2815-2830. https://doi.org/10.1080/01496399608000829

10.1080/01496399608000829
11

Kleineidam, S., Schüth, C., and Grathwohl, P., 2002, Solubilitynormalized combined adsorption-partitioning sorption isotherms for organic pollutants, Environ. Sci. Technol., 36(21), 4689-4697. https://doi.org/10.1021/es010293b

10.1021/es010293b
12

Krzyszczak, A., Dybowski, M.P., Zarzycki, R., Kobyłecki, R., Oleszczuk, P., and Czech, B., 2022, Long-term physical and chemical aging of biochar affected the amount and bioavailability of PAHs and their derivatives, J. Hazard. Mater., 440, 129795. https://doi.org/10.1016/j.jhazmat.2022.129795

10.1016/j.jhazmat.2022.129795
13

Luna, F.M.T., Oliveira Filho, A.N., Araújo, C.C.B., Azevedo, D.C.S., and Cavalcante, C.L., 2016. Adsorption of polycyclic aromatic hydrocarbons from heavy naphthenic oil using commercial activated carbons. 1. Fluid-Particle Studies, Ind. Eng. Chem. Res., 55(29), 8176-8183. https://doi.org/10.1021/acs.iecr.6b01059

10.1021/acs.iecr.6b01059
14

Masud, M.A. Al, Kim, D.G., and Shin, W.S., 2022, Degradation of phenol using Fe(II)-activated CaO2: effect of ball-milled activated carbon (ACBM) addition, Environ. Res., 214, 113882. https://doi.org/10.1016/j.envres.2022.113882

10.1016/j.envres.2022.113882
15

Niasar, H.S., Li, H., Kasanneni, T.V.R., Ray, M.B., and Xu, C.C., 2016, Surface amination of activated carbon and petroleum coke for the removal of naphthenic acids and treatment of oil sands process-affected water (OSPW), Chem. Eng. J., 293, 189-199. https://doi.org/10.1016/j.cej.2016.02.062

10.1016/j.cej.2016.02.062
17

Nyström, F., Nordqvist, K., Herrmann, I., Hedström, A., and Viklander, M., 2020, Removal of metals and hydrocarbons from stormwater using coagulation and flocculation, Water Res., 182, 115919. https://doi.org/10.1016/j.watres.2020.115919

10.1016/j.watres.2020.115919
18

Oh, S., Kwak, M.Y., and Shin, W.S., 2009, Competitive sorption of lead and cadmium onto sediments, Chem. Eng. J., 152(2-3), 376-388. https://doi.org/10.1016/j.cej.2009.04.061

10.1016/j.cej.2009.04.061
19

Pan, B., Lin, D., Mashayekhi, H., and Xing, B., 2008, Adsorption and hysteresis of bisphenol A and 17α-ethinyl estradiol on carbon nanomaterials, Environ. Sci. Technol., 42(15), 5480-5485. https://doi.org/10.1021/es8001184

10.1021/es8001184
20

Papageorgiou, S.K., Katsaros, F.K., Kouvelos, E.P., and Kanellopoulos, N.K., 2009, Prediction of binary adsorption isotherms of Cu2+, Cd2+ and Pb2+ on calcium alginate beads from single adsorption data, J. Hazard. Mater., 162(2-3), 1347-1354. https://doi.org/10.1016/j.jhazmat.2008.06.022

10.1016/j.jhazmat.2008.06.022
21

Pathak, S., Sakhiya, A.K., Anand, A., Pant, K.K., and Kaushal, P., 2022. A state-of-the-art review of various adsorption media employed for the removal of toxic Polycyclic aromatic hydrocarbons (PAHs): An approach towards a cleaner environment, J. Water Process Eng., 47, 102674. https://doi.org/10.1016/j.jwpe.2022.102674

10.1016/j.jwpe.2022.102674
22

Qiao, S. and Hu, X., 2000. Use IAST with MPSD to predict binary adsorption kinetics on activated carbon, AIChE J., 46(9), 1743-1752. https://doi.org/10.1002/aic.690460906

10.1002/aic.690460906
23

Shakya, A., Vithanage, M., and Agarwal, T., 2022, Influence of pyrolysis temperature on biochar properties and Cr(VI) adsorption from water with groundnut shell biochars: Mechanistic approach, Environ. Res., 215, 114243. https://doi.org/10.1016/j.envres.2022.114243

10.1016/j.envres.2022.114243
24

Shin, W.S. and Song, D.I., 2005. Solubility-normalized Freundlich isotherm for the prediction of sorption of phenols in HDTMA modified montmorillonite, Geosci. J., 9, 249-259. https://doi.org/10.1007/BF02910585

10.1007/BF02910585
25

Tran, H.N., You, S.-J., Hosseini-Bandegharaei, A., and Chao, H.-P., 2017, Mistakes and inconsistencies regarding adsorption of contaminants from aqueous solutions: A critical review, Water Res., 120, 88-116. https://doi.org/10.1016/j.watres.2017.04.014

10.1016/j.watres.2017.04.014
26

White, J.C., Hunter, M., Pignatello, J.J., and Alexander, M., 1999. Increase in bioavailability of aged phenanthrene in soils by competitive displacement with pyrene, Environ. Toxicol. Chem., 18(8), 1728-1732.

27

Yang, K., Zhu, L., and Xing, B., 2006, Adsorption of polycyclic aromatic hydrocarbons by carbon nanomaterials, Environ. Sci. Technol., 40(6), 1855-1861. https://doi.org/10.1021/es052208w

10.1021/es052208w
28

Zhu, M., Yao, J., Dong, L., and Sun, J., 2016, Adsorption of naphthalene from aqueous solution onto fatty acid modified walnut shells, Chemosphere, 144, 1639-1645. https://doi.org/10.1016/j.chemosphere.2015.10.050

10.1016/j.chemosphere.2015.10.050
Information
  • Publisher :The Korean Society of Soil and Groundwater Environment
  • Publisher(Ko) :한국지하수토양환경학회
  • Journal Title :Journal of Soil and Groundwater Environment
  • Journal Title(Ko) :지하수토양환경
  • Volume : 27
  • No :6
  • Pages :11-21
  • Received Date : 2022-11-04
  • Revised Date : 2022-11-14
  • Accepted Date : 2022-11-23
  • DOI :https://doi.org/10.7857/JSGE.2022.27.6.011
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