Effect of Acid Buffering Capacity and Soil Component Remediation of Soil Contaminated with Phenanthrene using Electrokinetic-Fenton Process

doi:10.7857/JSGE.2013.18.1.129

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2013 Vol.18, Issue 1 Preview Page Next Page

Effect of Acid Buffering Capacity and Soil Component Remediation of Soil Contaminated with Phenanthrene using Electrokinetic-Fenton Process 산 완충능력과 토양 성분이 동전기-펜톤 공정에 의한 phenanthrene 오염토양 정화에 미치는 영향: 김정환;나소정;박주양;변영덕;
Kim, Jung Hwan;Na, So Jeong;Park, Joo Yang;Byun, Young Deog;

28 February 2013. pp. 129 ~ 136

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Abstract

This research was conducted to investigate effects of acid buffering capacity and soil component in treatment of phenanthrene using electrokinetic-Fenton process. In Hadong clay of high acid buffering and low iron oxide content, it was difficult to oxidize phenanthrene due to shortage of iron catalyst and scavenger effect of carbonate minerals. The desorbed phenanthrene conductive to Fenton oxidation was transported toward cathode by electroosmotic flow. However, in Youngdong illitic clay, oxidation of phenanthrene near anode readily occurred compared to Hadong clay due to high iron content and low acid buffering capacity.

Keywords

Electrokinetic;Fenton oxidation;Remediation;Acid buffer capacity;Iron oxide;

References

Gee, C., Ramsey, M.H., and Thornton, I., 2001, Buffering fromsecondary minerals as a migration limiting factor in lead polluted soils at historical smelting sites, Appl. Geochem., 16, 1193-1199.10.1016/S0883-2927(01)00025-7
Hagg, W.R. and Yao, C., 1992, Rate constants for reaction of hydroxyl radicals with several drinking water contaminants. Environ. Sci. Technol., 26, 1005-1013.10.1021/es00029a021
Halmemies, S., Grondahl, S., Arffman, M., Neoonen, K., and Tuhkanen, T., 2003, Vaccum extraction based response equipment for recovery of fresh fuel spills from soil, J. Harzard. Mat., 97, 127-143.10.1016/S0304-3894(02)00249-2
Oonnittan, A., Isosaari, P., and Sillanpaa, M., 2010, Oxidant availability in soil and its effect on HCB removal during electrokinetic- Fenton proces, Sep. Purif. Technol., 76, 146-150.10.1016/j.seppur.2010.09.034
Kawahara, F.K., Davila, B., Al-Albed, S.R., Vesper, S.J. Ireland, J.C., and Rock, S., 1995, Polynuclear aromatic hydrocarbon (PAH) release from soil during treatment with Fenton's reagent, Chemosphere, 31, 4131-4142.10.1016/0045-6535(95)80013-B
Kim, J.H., Han, S.J., and Ki., S.S., 2006, Effect of soil chemical properties on the remediation of phenanthrene contaminated soil by electrokinetic-Fenton process, Chemosphere, 63, 1667-1676.10.1016/j.chemosphere.2005.10.008
Kim, S.S., Kim, J.H., and Han, S.J., 2005, Application of the electrokinetic-Fenton process for the remediation of kaolinite contaminated with phenanthrene, J. Hazrzard. Mater., 118, 121- 131.10.1016/j.jhazmat.2004.10.005
Kolthoff, I.M., Sandell, E.B., Meehan, E., and J. Buchkenstein, S., 1969 Quantitative Chemical Analysis. 4th Ed., Macmillan, New York, 842-860.
Saichek, R.E. and Reddy, K.R., 2003, Effect of pH control at the anode for the electrokinetic removal of phenanthrene from kaolin soil, Chemosphere, 51, 273-287.10.1016/S0045-6535(02)00849-4
Shapiro, A.P., Renaud, P.C., and Probstein, R.F., 1989, Preliminary studies on the removal of chemical species from saturated porous media by electroosmosis, PhysioChemical Hydrodynamics, 11, 785-802.
Tokalio lu, ., Kartal, ., and Elci, L., 2000, Determination of heavy metals and their speciation in lake sediments by flame atomic absorption spectrometry after a four-stage sequential extraction procedure, Anal. Chim. Acta, 413, 33-40.10.1016/S0003-2670(00)00726-1
Tyre, B.W., Watts, B.J., and Miller, G.C., 1991, Treatment of four biorefractory contaminants in soils using catalyzed hydrogen peroxide. J. Environ. Qual., 20, 832-838.
Tsai, T.T., Sah, J., and Kao, C.M., 2010, Application of iron electrode corrosion enhanced electrokinetic-Fenton oxidation to remediate diesel contaminated soil: a laboratory feasibility study, J. Hydrol., 380, 4-13.10.1016/j.jhydrol.2009.09.010
USEPA, 1995, How to evaluate alternative cleanup technologies for underground storage tank sites, Office of Solid Waste and Emergency Response, US Environmental Protection Agency, Publication # EPA 510-B-95-007.
USEPA, 1998, Office of the under underground storage tank, US Environmental Protection Agency, Publication # EPA 510- B-95-007.
Wada, S.I., and Umegaki, Y., 2001, Major ion and electrical potential distribution in soil under electrokinetic remediation, Eviron. Sci. Technol., 35, 2151-2155.10.1021/es001335j
Walling, C., 1975, Fentons reagent revisited. Accounts Chem. Res., 8, 125-131.10.1021/ar50088a003
Walkley, A. and Black, I.A., 1934, An examination of the digestion method for determining soil organic matter and a proposed modification of the chromic acid titration method, Soil Sci., 37, 29-38.10.1097/00010694-193401000-00003
Yeung, A.T., 2011, Milestone developments, mythys, and future directions of electrokinetic remediation, Sep. Purif. Technol. 79, 124-132.10.1016/j.seppur.2011.01.022
Yong, R. and Warkentin, B.P., 1990, Buffer capacity and lead retention in some clay materials, Water, Air, and Soil Pollution, 53, 53-67.

Information

Publisher :The Korean Society of Soil and Groundwater Environment
Publisher(Ko) :한국지하수토양환경학회
Journal Title :Journal of Soil and Groundwater Environment
Journal Title(Ko) :지하수토양환경
Volume : 18
No :1
Pages :129 ~ 136
DOI :https://doi.org/10.7857/JSGE.2013.18.1.129

[1] Gee, C., Ramsey, M.H., and Thornton, I., 2001, Buffering fromsecondary minerals as a migration limiting factor in lead polluted soils at historical smelting sites, Appl. Geochem., 16, 1193-1199.10.1016/S0883-2927(01)00025-7

[2] Hagg, W.R. and Yao, C., 1992, Rate constants for reaction of hydroxyl radicals with several drinking water contaminants. Environ. Sci. Technol., 26, 1005-1013.10.1021/es00029a021

[3] Halmemies, S., Grondahl, S., Arffman, M., Neoonen, K., and Tuhkanen, T., 2003, Vaccum extraction based response equipment for recovery of fresh fuel spills from soil, J. Harzard. Mat., 97, 127-143.10.1016/S0304-3894(02)00249-2

[4] Oonnittan, A., Isosaari, P., and Sillanpaa, M., 2010, Oxidant availability in soil and its effect on HCB removal during electrokinetic- Fenton proces, Sep. Purif. Technol., 76, 146-150.10.1016/j.seppur.2010.09.034

[5] Kawahara, F.K., Davila, B., Al-Albed, S.R., Vesper, S.J. Ireland, J.C., and Rock, S., 1995, Polynuclear aromatic hydrocarbon (PAH) release from soil during treatment with Fenton's reagent, Chemosphere, 31, 4131-4142.10.1016/0045-6535(95)80013-B

[6] Kim, J.H., Han, S.J., and Ki., S.S., 2006, Effect of soil chemical properties on the remediation of phenanthrene contaminated soil by electrokinetic-Fenton process, Chemosphere, 63, 1667-1676.10.1016/j.chemosphere.2005.10.008

[7] Kim, S.S., Kim, J.H., and Han, S.J., 2005, Application of the electrokinetic-Fenton process for the remediation of kaolinite contaminated with phenanthrene, J. Hazrzard. Mater., 118, 121- 131.10.1016/j.jhazmat.2004.10.005

[8] Kolthoff, I.M., Sandell, E.B., Meehan, E., and J. Buchkenstein, S., 1969 Quantitative Chemical Analysis. 4th Ed., Macmillan, New York, 842-860.

[9] Saichek, R.E. and Reddy, K.R., 2003, Effect of pH control at the anode for the electrokinetic removal of phenanthrene from kaolin soil, Chemosphere, 51, 273-287.10.1016/S0045-6535(02)00849-4

[10] Shapiro, A.P., Renaud, P.C., and Probstein, R.F., 1989, Preliminary studies on the removal of chemical species from saturated porous media by electroosmosis, PhysioChemical Hydrodynamics, 11, 785-802.

[11] Tokalio lu, ., Kartal, ., and Elci, L., 2000, Determination of heavy metals and their speciation in lake sediments by flame atomic absorption spectrometry after a four-stage sequential extraction procedure, Anal. Chim. Acta, 413, 33-40.10.1016/S0003-2670(00)00726-1

[12] Tyre, B.W., Watts, B.J., and Miller, G.C., 1991, Treatment of four biorefractory contaminants in soils using catalyzed hydrogen peroxide. J. Environ. Qual., 20, 832-838.

[13] Tsai, T.T., Sah, J., and Kao, C.M., 2010, Application of iron electrode corrosion enhanced electrokinetic-Fenton oxidation to remediate diesel contaminated soil: a laboratory feasibility study, J. Hydrol., 380, 4-13.10.1016/j.jhydrol.2009.09.010

[14] USEPA, 1995, How to evaluate alternative cleanup technologies for underground storage tank sites, Office of Solid Waste and Emergency Response, US Environmental Protection Agency, Publication # EPA 510-B-95-007.

[15] USEPA, 1998, Office of the under underground storage tank, US Environmental Protection Agency, Publication # EPA 510- B-95-007.

[16] Wada, S.I., and Umegaki, Y., 2001, Major ion and electrical potential distribution in soil under electrokinetic remediation, Eviron. Sci. Technol., 35, 2151-2155.10.1021/es001335j

[17] Walling, C., 1975, Fentons reagent revisited. Accounts Chem. Res., 8, 125-131.10.1021/ar50088a003

[18] Walkley, A. and Black, I.A., 1934, An examination of the digestion method for determining soil organic matter and a proposed modification of the chromic acid titration method, Soil Sci., 37, 29-38.10.1097/00010694-193401000-00003

[19] Yeung, A.T., 2011, Milestone developments, mythys, and future directions of electrokinetic remediation, Sep. Purif. Technol. 79, 124-132.10.1016/j.seppur.2011.01.022

[20] Yong, R. and Warkentin, B.P., 1990, Buffer capacity and lead retention in some clay materials, Water, Air, and Soil Pollution, 53, 53-67.

Journal of Soil and Groundwater Environment ISSN:1598-6438(Print) 2287-8831(Online) 지하수토양환경

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