The Effect of Distance between Two Transducers on Sonochemical Reactions in Dual Irradiation Systems

doi:10.7857/JSGE.2013.18.5.039

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2013 Vol.18, Issue 5 Preview Page Next Page

The Effect of Distance between Two Transducers on Sonochemical Reactions in Dual Irradiation Systems 이중 초음파 조사 시스템에서 진동부 사이의 거리가 초음파 화학 반응에 미치는 영향: 김은경;손영규;
Kim, Eunkyung;Son, Younggyu;

31 October 2013. pp. 39 ~ 45

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Abstract

Many researchers have studied the effectiveness of ultrasound in chemical and environmental engineering fields including material synthesis, pollutant removal, cleaning, extraction, and disinfection. Acoustic cavitation induced by ultrasound irradiation in aqueous phase can cause various sonophysical and sonochemical reactions without any chemicals. However most of the previous studies focused only on the relationships between ultrasonic conditions and the results of sonochemical reactions in lab-scale sonoreactors. As a results of this, only a few studies have been devoted to design and optimization of industrial scale sonoreactors. In this study, the effect of the distance between two opposite transducer modules on sonochemical reactions was investigated in single and dual irradiation systems (334 kHz) for four distances including 50, 100, 150, and 200 mm using KI dosimetry. It was found that the dual irradiation systems provided higher performance in terms of the zeroth reaction coefficient and the cavitation yield compared to the single irradiation systems. The sonochemiluminescence (SCL) images for the visualization of the cavitation field showed that cavitation active zone was larger and sonochemical reaction intensity was much higher in the dual irradiation system than in the single irradiation system.

Keywords

Sonochemical reaction;Single irradiation;Dual irradiation;Cavitation yield;Sonochemiluminescence (SCL);

References

Adewuyi, Y.G., 2001, Sonochemistry: Environmental Science and Engineering Applications, Ind. Eng. Chem. Res., 40(22), 4681-4715.10.1021/ie010096l
Asakura, Y., Nishida, T., Matsuoka, T., and Koda, S., 2008, Effects of ultrasonic frequency and liquid height on sonochemical efficiency of large-scale sonochemical reactors, Ultrason. Sonochem., 15(3), 244-250.10.1016/j.ultsonch.2007.03.012
Kanthale, P.M., Brotchie, A., Ashokkumar, M., and Grieser, F., 2008, Experimental and theoretical investigations on sonoluminescence under dual frequency conditions. Ultrason. Sonochem., 15(4), 629-635.10.1016/j.ultsonch.2007.08.006
Lee, M. and Oh, J., 2010, Sonolysis of trichloroethylene and carbon tetrachloride in aqueous solution, Ultrason. Sonochem., 17(1), 207-212.10.1016/j.ultsonch.2009.06.018
Lim, M., Son, Y., Cui, M., and Khim, J., 2009, Effects of Hydrogen Peroxide and Frequency for the Sonochemical Degradation of Aqueous Phenol, J. J. Appl. Phys., 48(7), 07GH07.
Lim, M., Son, Y., and Khim, J., 2011, Frequency effects on the sonochemical degradation of chlorinated compounds. Ultrason. Sonochem., 18(1), 460-465.10.1016/j.ultsonch.2010.07.021
Mason, T.J. and Lorimer, J.P., 2002, Applied Sonochemistry- The Uses of Power Ultrasound in Chemistry and Processing, Wiley-VCH Verlag GmbH: Weinheim.
Son, Y., Lim, M., Cui, M., and Khim, J., 2010, Estimation of Sonochemical Reactions under Single and Dual Frequencies Based on Energy Analysis, J. Appl. Phys., 49(7), 07HE02.
Son, Y., Lim, J., Cui, M., Lim, M., Kweon, B.Y., and Khim, J., 2009a, Application of Ultrasound and Ozone for the Removal of Aqueous Tannin, J. J. Appl. Phys., 48(7), 07GH05.
Son, Y., Lim, M., and Khim, J., 2009b, Investigation of acoustic cavitation energy in a large-scale sonoreactor, Ultrason. Sonochem., 16(4), 552-556.10.1016/j.ultsonch.2008.12.004
Son, Y., Lim, M., Ashokkumar, M., and Khim, J., 2011, Geometric Optimization of Sonoreactors for the Enhancement of Sonochemical Activity, J. Phys. Chem. C, 115(10), 4096-4103.10.1021/jp110319y
Son, Y., Lim, M., Khim, J., and Ashokkumar, M., 2012, Attenuation of UV Light in Large-Scale Sonophotocatalytic Reactors: The Effects of Ultrasound Irradiation and $TiO_2$ Concentration, Ind. Eng. Chem. Res., 51(1), 232-239.10.1021/ie202401z
Torres, R.A., Nieto, J.I., Combet, E., Ptrier, C., and Pulgarin, C., 2008, Influence of $TiO_2$ concentration on the synergistic effect between photocatalysis and high-frequency ultrasound for organic pollutant mineralization in water, Appl. Catal. B: Environ., 80(1-2), 168-175.10.1016/j.apcatb.2007.11.013
Zhao, L., Ma, J., and Zhai, X., 2009, Synergetic effect of ultrasound with dual fields for the degradation of nitrobenzene in aqueous solution, Environ. Sci. Technol., 43(13), 5094-5099.10.1021/es9003334

Information

Publisher :The Korean Society of Soil and Groundwater Environment
Publisher(Ko) :한국지하수토양환경학회
Journal Title :Journal of Soil and Groundwater Environment
Journal Title(Ko) :지하수토양환경
Volume : 18
No :5
Pages :39 ~ 45
DOI :https://doi.org/10.7857/JSGE.2013.18.5.039

[1] Adewuyi, Y.G., 2001, Sonochemistry: Environmental Science and Engineering Applications, Ind. Eng. Chem. Res., 40(22), 4681-4715.10.1021/ie010096l

[2] Asakura, Y., Nishida, T., Matsuoka, T., and Koda, S., 2008, Effects of ultrasonic frequency and liquid height on sonochemical efficiency of large-scale sonochemical reactors, Ultrason. Sonochem., 15(3), 244-250.10.1016/j.ultsonch.2007.03.012

[3] Kanthale, P.M., Brotchie, A., Ashokkumar, M., and Grieser, F., 2008, Experimental and theoretical investigations on sonoluminescence under dual frequency conditions. Ultrason. Sonochem., 15(4), 629-635.10.1016/j.ultsonch.2007.08.006

[4] Lee, M. and Oh, J., 2010, Sonolysis of trichloroethylene and carbon tetrachloride in aqueous solution, Ultrason. Sonochem., 17(1), 207-212.10.1016/j.ultsonch.2009.06.018

[5] Lim, M., Son, Y., Cui, M., and Khim, J., 2009, Effects of Hydrogen Peroxide and Frequency for the Sonochemical Degradation of Aqueous Phenol, J. J. Appl. Phys., 48(7), 07GH07.

[6] Lim, M., Son, Y., and Khim, J., 2011, Frequency effects on the sonochemical degradation of chlorinated compounds. Ultrason. Sonochem., 18(1), 460-465.10.1016/j.ultsonch.2010.07.021

[7] Mason, T.J. and Lorimer, J.P., 2002, Applied Sonochemistry- The Uses of Power Ultrasound in Chemistry and Processing, Wiley-VCH Verlag GmbH: Weinheim.

[8] Son, Y., Lim, M., Cui, M., and Khim, J., 2010, Estimation of Sonochemical Reactions under Single and Dual Frequencies Based on Energy Analysis, J. Appl. Phys., 49(7), 07HE02.

[9] Son, Y., Lim, J., Cui, M., Lim, M., Kweon, B.Y., and Khim, J., 2009a, Application of Ultrasound and Ozone for the Removal of Aqueous Tannin, J. J. Appl. Phys., 48(7), 07GH05.

[10] Son, Y., Lim, M., and Khim, J., 2009b, Investigation of acoustic cavitation energy in a large-scale sonoreactor, Ultrason. Sonochem., 16(4), 552-556.10.1016/j.ultsonch.2008.12.004

[11] Son, Y., Lim, M., Ashokkumar, M., and Khim, J., 2011, Geometric Optimization of Sonoreactors for the Enhancement of Sonochemical Activity, J. Phys. Chem. C, 115(10), 4096-4103.10.1021/jp110319y

[12] Son, Y., Lim, M., Khim, J., and Ashokkumar, M., 2012, Attenuation of UV Light in Large-Scale Sonophotocatalytic Reactors: The Effects of Ultrasound Irradiation and $TiO_2$ Concentration, Ind. Eng. Chem. Res., 51(1), 232-239.10.1021/ie202401z

[13] Torres, R.A., Nieto, J.I., Combet, E., Ptrier, C., and Pulgarin, C., 2008, Influence of $TiO_2$ concentration on the synergistic effect between photocatalysis and high-frequency ultrasound for organic pollutant mineralization in water, Appl. Catal. B: Environ., 80(1-2), 168-175.10.1016/j.apcatb.2007.11.013

[14] Zhao, L., Ma, J., and Zhai, X., 2009, Synergetic effect of ultrasound with dual fields for the degradation of nitrobenzene in aqueous solution, Environ. Sci. Technol., 43(13), 5094-5099.10.1021/es9003334

Journal of Soil and Groundwater Environment ISSN:1598-6438(Print) 2287-8831(Online) 지하수토양환경

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