A Study on the Removal of Heavy Metals in Soil by Sewage Sludge Biochar

doi:10.7857/JSGE.2013.18.3.058

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2013 Vol.18, Issue 3 Preview Page Next Page

A Study on the Removal of Heavy Metals in Soil by Sewage Sludge Biochar 하수슬러지의 Biochar특성을 이용한 토양내 중금속 제거 연구: 김혜원;배선영;이재영;
Kim, Hye-Won;Bae, Sunyoung;Lee, Jai-Young;

30 June 2013. pp. 58 ~ 64

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Abstract

This study proposed a low temperature hydrothermal carbonization to treat and recycle sewage sludge and determined the optimal conditions for the biochar production. The physical and chemical properties of biochar were analyzed and its sorption capacity for heavy metals was evaluated. To produce biochar, 50 g of sewage sludge was heated at 220, 230, and $240^{\circ}C$ for 1, 2, 3, 5, 8, and 10 hours in a reactor. The optimal conditions to produce biochar was $230^{\circ}C$ and 8 hours. Sorption capacity tests were conducted for arsenic (As), cadmium (Cd), copper (Cu), lead (Pb), zinc (Zn) and nickel (Ni). Among them, lead was shown the highest heavy metal adsorption efficiency of biochar, followed by copper, cadmium, zinc, and nickel, but arsenic was hardly adsorbed overall.

Keywords

HTC (Hydrothermal Carbonization);Biochar;Sewage sludge;Heavy metal adsorption;

References

Bae, S. and Koh, E., 2011, Lead and Zinc Sorption in Biochar of Cabbage using Hydrothermal Carbonization, The Korea Society for Environmental Analysis, 14(4), 228-233.
Baek. Y.S., 2012, The characteristics of the Bio-char with the food and wood waste, Master's degree dissertation, Department of Environmental Engineering, University of Seoul.
Beesley, L. and Marmiroli, M., 2011, The immobilisation and retention of soluble arsenic, cadmium and zinc by biochar, Environmental Pollution, 159(2), 474-480.10.1016/j.envpol.2010.10.016
Berge, N.D., Ro, K.S., Mao, J., Flora, J.R.V., Chappell, M.A., and Bae, S., 2011, Hydrothermal Carbonization of Municipal Waste Streams, Env. Sci. Technol., 45(13), 5696-5703.10.1021/es2004528
Elliott, H.A., Liberati, M.R., and Huang C.P., 1986, Competitive Adsorption of Heavy Metals by Soils, J. Environ. Qual., 15(3), 214-219.
Girgis, B.S., Khalil, L.B., and Tawfik, T.A.M., 1994, Activated Carbon from Sugar Cane Bagasse by Carbonization in the Presence of Inorganic acids, J. Chem. Technol. Biot., 61(1), 87-92.10.1002/jctb.280610113
Guo, J. and Lua, A.C., 1998, Characterization of chars pyrolyzed from oil palm stones for the preparation of activated carbons, J. Anal. Appl. Pyrol., 46(2), 113-125.10.1016/S0165-2370(98)00074-6
Hossain, M.K., Strezov V., Chan, K.Y., and Nelson, P.F., 2010, Agronomic properties of wastewater sludge biochar and bioavailability of metals in production of cherry tomato (Lycopersicon esculentum), Chemosphere, 78(9), 1167-1171.10.1016/j.chemosphere.2010.01.009
Jung, D., Baek, W., Kim, S., and Chun, Y., 2008, Adsorption Characteristics of Sewage Sludge Prepared by Physical and Chemical Activation, J. A., 1(1), 91-97.
Kim, M., Ham1, K., Ok, Y., and Gang S., 2010, Adsorption Characteristics of Cadmium ions from Aqueous Solution using by-product of Brewing, Korean Journal of Environmental Agriculture, 29(2), 152-158.10.5338/KJEA.2010.29.2.152
Kim, H., Chon, H., Lee, J., and Roh, Y., 2011, Adsorptive removal of aqueous arsenic using nanoparticles of iron hydroxides, J. KSGE, 48(4), 438-447.
Korean Industrial Standards, 2009, Test methods for activated carbon, KS M 1802.
Kumar, S., Loganathan, V.A., Gupta, R.B., and Barnett, M.O., 2011, An Assessment of U(VI) removal from froundwater using biochar produced from hydrtothermal carbonization, J. Environ Manage, 92(10), 2504-2512.10.1016/j.jenvman.2011.05.013
Lee, S., Dyer, J.A., Sparks, D.L., Scivner, N.C., and Elzinga, E.J., 2006, A multi-scale Assessment of Pb(II) Sorption on Dolomite, J. Colloid. Interface Sci., 298, 20-30.10.1016/j.jcis.2005.12.022
Lehmann, J. and Joseph, S., 2009, Biochar for Environmental Management(Science and Technology): Taylor &Francis, Sterling, VA, p. 127-143.
Ministry of Environment, 2011, Census of sewerage 2011.
Ministry of Environment, 2011, Wastes Control Act, Enforcement regulations.
Mohan, D., Pittman, C.U., Bricka, M., Smith, F., Yancey, B., Mohammad, J., Steele, P.H., Alexandre-Franco, M.F., Gomez-Serrano, V., and Gong, H., 2007, Sorption of arsenic, cadmium, and lead by chars produced from fast pyrolysis of wood and bark during bio-oil production, J. Colloid. Inter. Sci., 310(1), 57-73.10.1016/j.jcis.2007.01.020
Nam, Y.W. and Han, K.S., 2011, A Study on the Present State and Improvement Plan of Domestic Sewage Sludge Treatment, Korea society of waste management, 28(1), 103-109.
Park, S.K., Kim, H.N., and Kim, Y.K., 2007, Efficacy of Cu(II) Adsorption by Chemical Modification of Pine Bark, J. of KSEE, 29(8), 930-937.
Solomon, D., Lehmann, J., Thies, J., Schafer, T., Liang, B., Kin-yangi, J., Neve as, E., Petersen J., Luizo, F., and Skjemstad, J., 2007, Molecular signature and sources of biochemical recalcitrance of organic C in Amazonian Dark Earths, Geochimica et Cosmochimica Acta, 71, 2285-2298.10.1016/j.gca.2007.02.014
Titirici, M.M., Thomas, A., Yu, S.-H., Muller, J.-O., and Antonietti, M., 2007, A Direct Synthesis of Mesoporous Carbons with Bicontinuous Pore Morphology from Crude Plant Material by Hydrothermal Carbonization, Chemistry of materials, 19(17), 4205-4212.10.1021/cm0707408
USEPA, 1992, Batch-type procedures for American Society for Testing and Materials (ASTM D-4646).

Information

Publisher :The Korean Society of Soil and Groundwater Environment
Publisher(Ko) :한국지하수토양환경학회
Journal Title :Journal of Soil and Groundwater Environment
Journal Title(Ko) :지하수토양환경
Volume : 18
No :3
Pages :58 ~ 64
DOI :https://doi.org/10.7857/JSGE.2013.18.3.058

[1] Bae, S. and Koh, E., 2011, Lead and Zinc Sorption in Biochar of Cabbage using Hydrothermal Carbonization, The Korea Society for Environmental Analysis, 14(4), 228-233.

[2] Baek. Y.S., 2012, The characteristics of the Bio-char with the food and wood waste, Master's degree dissertation, Department of Environmental Engineering, University of Seoul.

[3] Beesley, L. and Marmiroli, M., 2011, The immobilisation and retention of soluble arsenic, cadmium and zinc by biochar, Environmental Pollution, 159(2), 474-480.10.1016/j.envpol.2010.10.016

[4] Berge, N.D., Ro, K.S., Mao, J., Flora, J.R.V., Chappell, M.A., and Bae, S., 2011, Hydrothermal Carbonization of Municipal Waste Streams, Env. Sci. Technol., 45(13), 5696-5703.10.1021/es2004528

[5] Elliott, H.A., Liberati, M.R., and Huang C.P., 1986, Competitive Adsorption of Heavy Metals by Soils, J. Environ. Qual., 15(3), 214-219.

[6] Girgis, B.S., Khalil, L.B., and Tawfik, T.A.M., 1994, Activated Carbon from Sugar Cane Bagasse by Carbonization in the Presence of Inorganic acids, J. Chem. Technol. Biot., 61(1), 87-92.10.1002/jctb.280610113

[7] Guo, J. and Lua, A.C., 1998, Characterization of chars pyrolyzed from oil palm stones for the preparation of activated carbons, J. Anal. Appl. Pyrol., 46(2), 113-125.10.1016/S0165-2370(98)00074-6

[8] Hossain, M.K., Strezov V., Chan, K.Y., and Nelson, P.F., 2010, Agronomic properties of wastewater sludge biochar and bioavailability of metals in production of cherry tomato (Lycopersicon esculentum), Chemosphere, 78(9), 1167-1171.10.1016/j.chemosphere.2010.01.009

[9] Jung, D., Baek, W., Kim, S., and Chun, Y., 2008, Adsorption Characteristics of Sewage Sludge Prepared by Physical and Chemical Activation, J. A., 1(1), 91-97.

[10] Kim, M., Ham1, K., Ok, Y., and Gang S., 2010, Adsorption Characteristics of Cadmium ions from Aqueous Solution using by-product of Brewing, Korean Journal of Environmental Agriculture, 29(2), 152-158.10.5338/KJEA.2010.29.2.152

[11] Kim, H., Chon, H., Lee, J., and Roh, Y., 2011, Adsorptive removal of aqueous arsenic using nanoparticles of iron hydroxides, J. KSGE, 48(4), 438-447.

[12] Korean Industrial Standards, 2009, Test methods for activated carbon, KS M 1802.

[13] Kumar, S., Loganathan, V.A., Gupta, R.B., and Barnett, M.O., 2011, An Assessment of U(VI) removal from froundwater using biochar produced from hydrtothermal carbonization, J. Environ Manage, 92(10), 2504-2512.10.1016/j.jenvman.2011.05.013

[14] Lee, S., Dyer, J.A., Sparks, D.L., Scivner, N.C., and Elzinga, E.J., 2006, A multi-scale Assessment of Pb(II) Sorption on Dolomite, J. Colloid. Interface Sci., 298, 20-30.10.1016/j.jcis.2005.12.022

[15] Lehmann, J. and Joseph, S., 2009, Biochar for Environmental Management(Science and Technology): Taylor &Francis, Sterling, VA, p. 127-143.

[16] Ministry of Environment, 2011, Census of sewerage 2011.

[17] Ministry of Environment, 2011, Wastes Control Act, Enforcement regulations.

[18] Mohan, D., Pittman, C.U., Bricka, M., Smith, F., Yancey, B., Mohammad, J., Steele, P.H., Alexandre-Franco, M.F., Gomez-Serrano, V., and Gong, H., 2007, Sorption of arsenic, cadmium, and lead by chars produced from fast pyrolysis of wood and bark during bio-oil production, J. Colloid. Inter. Sci., 310(1), 57-73.10.1016/j.jcis.2007.01.020

[19] Nam, Y.W. and Han, K.S., 2011, A Study on the Present State and Improvement Plan of Domestic Sewage Sludge Treatment, Korea society of waste management, 28(1), 103-109.

[20] Park, S.K., Kim, H.N., and Kim, Y.K., 2007, Efficacy of Cu(II) Adsorption by Chemical Modification of Pine Bark, J. of KSEE, 29(8), 930-937.

[21] Solomon, D., Lehmann, J., Thies, J., Schafer, T., Liang, B., Kin-yangi, J., Neve as, E., Petersen J., Luizo, F., and Skjemstad, J., 2007, Molecular signature and sources of biochemical recalcitrance of organic C in Amazonian Dark Earths, Geochimica et Cosmochimica Acta, 71, 2285-2298.10.1016/j.gca.2007.02.014

[22] Titirici, M.M., Thomas, A., Yu, S.-H., Muller, J.-O., and Antonietti, M., 2007, A Direct Synthesis of Mesoporous Carbons with Bicontinuous Pore Morphology from Crude Plant Material by Hydrothermal Carbonization, Chemistry of materials, 19(17), 4205-4212.10.1021/cm0707408

[23] USEPA, 1992, Batch-type procedures for American Society for Testing and Materials (ASTM D-4646).

Journal of Soil and Groundwater Environment ISSN:1598-6438(Print) 2287-8831(Online) 지하수토양환경

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