Field Study on Application of Reactive Zone Technology Using Zero-Valent Iron Nanoparticles for Remediation of TCE-Contaminated Groundwater

doi:10.7857/JSGE.2014.19.6.080

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2014 Vol.19, Issue 6 Preview Page

Field Study on Application of Reactive Zone Technology Using Zero-Valent Iron Nanoparticles for Remediation of TCE-Contaminated Groundwater TCE 오염 지하수의 정화를 위한 나노영가철 기반 반응존 공법의 현장 적용성 연구: 안준영;김철용;황경엽;전성천;황인성;
Ahn, Jun-Young;Kim, Cheolyong;Hwang, Kyung-Yup;Jun, Seong-Chun;Hwang, Inseong;

31 December 2014. pp. 80 ~ 90

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Abstract

The laboratory and field studies were conducted to identify an optimal injection concentration of nanoscale zero-valent iron particles (NZVI) and to evaluate the applicability of NZVI-based reactive zone technology to the site contaminated with trichloroethylene (TCE) DNAPL (Dense Non-Aqueous Phase Liquid). The laboratory test found an optimal injection concentration of NZVI of 5 g/L that could remove more than 95% of 0.15 mM TCE within 20 days. Eleven test wells were installed at the aquifer that was mainly composed of alluvial and weathered soils at a strong oxic condition with dissolved oxygen concentration of 3.50 mg/L and oxidation-reduction potential of 301 mV. NZVI of total 30 kg were successfully injected using a centrifugal pump. After 60 days from the NZVI injection, 86.2% of the TCE initially present in the groundwater was removed and the mass of TCE removed was 405 g. Nonchlorinated products such as ethane and ethene were detected in the groundwater samples. Based on the increased chloride ion concentration at the site, the mass of TCE removed was estimated to be 1.52 kg. This implied the presence of DNAPL TCE which contributed to a higher estimate of TCE removal than that based on the TCE concentration change.

Keywords

Nanoscale zero-valent iron;In situ chemical reduction;DNAPL;Groundwater remediation;Trichloroethylene;

References

Bacelona, M.J., Gibb, J.P., Helfrich, J.A., and Garske, E.E., 1985, Practical guide for ground-water sampling, SWS Contract Report 374, 94 p.
Elliott, D.W. and Zhang, W., 2001, Field assessment of nanoscale bimetallic particles for groundwater treatment, Environ. Sci. Technol., 35(24), 4922-4926.10.1021/es0108584
Hara, S.O., Krug, T., Quinn, J., Clausen, C., and Geiger, C., 2006, Field and laboratory evaluation of the treatment of DNAPL source zones using emulsified zerovalent iron, Remed. J., 16(2), 35-56.10.1002/rem.20080
He, F., Zhao, D., Liu, J., and Roberts, C.B., 2007, Stabilization of Fe-Pd nanoparticles with sodium carboxymethyl cellulose for enhanced transport and dechlorination of trichloroethylene in soil and groundwater, Ind. Eng. Chem. Res., 46(1), 29-34.10.1021/ie0610896
Jiemvarangkul, P., Zhang, W., and Lien, H., 2011, Enhanced transport of polyelectrolyte stabilized nanoscale zero-valent iron (NZVI) in porous media, Chem. Eng. J., 170(2), 482-491.10.1016/j.cej.2011.02.065
Jo, Y.J., Lee, J.Y., Jun, S.C., Cheon, J.Y., and Kwon, H.P., 2010, Estimation of hydraulic parameters from slug, single well pumping and step-drawdown tests, J. Eng. Geol., 20(2), 203-212.
Johnson, R.L., Johmson, G.O., Nurmi, J.T., and Tratnyet, P.G., 2009, Natural organic matter enhanced mobility of nano zerovalent iron, Environ. Sci. Technol., 43, 5455-5460.10.1021/es900474f
Kim, C., Ahn, J.Y., Ngoc, T.H., Kim, H.S., Jun, S.C., and Hwang, I., 2013, Characterization of the transport of zero-valent iron nanoparticles in an aquifer for application of reactive zone technology, J. Soil Groundw. Environ., 18(3), 109-118.10.7857/JSGE.2013.18.3.109
Kim, H.S., Ahn, J.Y., Hwang, K.Y., Kim, I.K., and Hwang I., 2010, Atmospherically stable nanoscale zero-valent iron particles formed under controlled air contact: characterisitcs and reactivity, Environ. Sci. Technol., 44, 1760-1766.10.1021/es902772r
Kim, H.S., Ahn, J.Y., Kim, C., Lee, S., and Hwang, I., 2014, Effect of anions and humic acid on the performance of nanoscale zero-valent iron particles coated with polyacryic acid, Chemosphere. 113, 93-100.10.1016/j.chemosphere.2014.04.047
Kim, H.S., Kim, T., Ahn, J.Y., Hwang, K.Y., Park, J.Y., Lim, T.T., and Hwang I., 2012, Aging characteristics reactivity of two types of nanoscale zero-valent iron particles ($Fe^{BH}$ and $Fe^{H2}$) in nitrate reduction, Chem. Eng. J., 197, 16-23.10.1016/j.cej.2012.05.018
Kim, T., Kim, H., Lee, J., Cheon, J., Lee, K., and Hwang, I., 2011, Effect of dissolved compounds in groundwater on TCE degradations reaction by nanoscale Zero-valent iron, Kor. Soc. Econ. Environ. Geol., 33(6), 413-419.
Klimkova, S., Cernik, M., Lacinova, L., Filip, J., Jancik, D., and Zboril, R., 2011, Zero-valent iron nanoparticles in treatment of acid mine water from in situ uranium leaching, Chemosphere, 82(8), 1178-1184.10.1016/j.chemosphere.2010.11.075
Korean Ministry of Environment, 2012, Operating report of groundwater monitoring system in 2011.
MacDonald, J.A. and Kavanaugh, M.C., 1994, Restoring contaminated groundwater: an achievable goal?, Environ. Sci. Technol., 28(8), 362A-368A.
Phenrat, T., Saleh, N., Sirk, K., Tilton, R.D., and Lowry, G.V., 2007, Aggregation and sedimentation of aqueous nanoscale zerovalent iron dispersions, Environ. Sci. Technol., 41(1), 284-290.10.1021/es061349a
Quinn, J., Geiger, C., Clausen, C., O'hara, S., Krug, T., Major, D., Yoon, W.S., and Holdsworth, T., 2005, Field demonstration of DNAPL dehalogenation using emulsified zero-valent iron, Environ. Sci. Technol., 39, 1309-1318.10.1021/es0490018
Saleh, N., Kim, H., Phenrat, T., Matyjaszewski, K., Tilton, R.D., and Lowry, G.V., 2008, Ionic strength and composition affect the mobility of surface-modified $Fe^0$ nanoparticles in water-saturated sand columns, Environ. Sci. Technol., 42(9), 3349-3355.10.1021/es071936b
Saleh, N., Phenrat, T., Sirl, K., Dufour, B., Ok, J., Sarbu, T., Matyjaszewski, K., Tilton, R.D., and Lowry, G.V., 2005, Adsorbed triblock copolymers deliver reactive iron nanoparticles to the oil/water interface, Nano Lett., 5(12), 2489-2494.10.1021/nl0518268
Sun, Y.P., Li, X.Q., Zhang, W.X. and Wang, H.P., 2007, A method for the preparation of stable dispersion of zero-valent iron nanoparticles, Colloids Surf., A, 308, 60-66.10.1016/j.colsurfa.2007.05.029
Wei, Y., Wu, S., Chou, C., Che, C., Tsai, S., and Lien, H., 2010, Influence of nanoscale zero-valent iron on geochemical properties of groundwater and vinyl chloride degradation: A field case study, Water Res., 44(1), 131-140.10.1016/j.watres.2009.09.012
Zhang, W., Quan, W., Wang, J., Zhang, Z., and Chen, S., 2006, Rapid and complete dechlorination of PCP in aqueous solution using Ni-Fe nanoparticles under assistance of ultrasound, Chemosphere, 65, 58-64.10.1016/j.chemosphere.2006.02.060

Information

Publisher :The Korean Society of Soil and Groundwater Environment
Publisher(Ko) :한국지하수토양환경학회
Journal Title :Journal of Soil and Groundwater Environment
Journal Title(Ko) :지하수토양환경
Volume : 19
No :6
Pages :80 ~ 90
DOI :https://doi.org/10.7857/JSGE.2014.19.6.080

[1] Bacelona, M.J., Gibb, J.P., Helfrich, J.A., and Garske, E.E., 1985, Practical guide for ground-water sampling, SWS Contract Report 374, 94 p.

[2] Elliott, D.W. and Zhang, W., 2001, Field assessment of nanoscale bimetallic particles for groundwater treatment, Environ. Sci. Technol., 35(24), 4922-4926.10.1021/es0108584

[3] Hara, S.O., Krug, T., Quinn, J., Clausen, C., and Geiger, C., 2006, Field and laboratory evaluation of the treatment of DNAPL source zones using emulsified zerovalent iron, Remed. J., 16(2), 35-56.10.1002/rem.20080

[4] He, F., Zhao, D., Liu, J., and Roberts, C.B., 2007, Stabilization of Fe-Pd nanoparticles with sodium carboxymethyl cellulose for enhanced transport and dechlorination of trichloroethylene in soil and groundwater, Ind. Eng. Chem. Res., 46(1), 29-34.10.1021/ie0610896

[5] Jiemvarangkul, P., Zhang, W., and Lien, H., 2011, Enhanced transport of polyelectrolyte stabilized nanoscale zero-valent iron (NZVI) in porous media, Chem. Eng. J., 170(2), 482-491.10.1016/j.cej.2011.02.065

[6] Jo, Y.J., Lee, J.Y., Jun, S.C., Cheon, J.Y., and Kwon, H.P., 2010, Estimation of hydraulic parameters from slug, single well pumping and step-drawdown tests, J. Eng. Geol., 20(2), 203-212.

[7] Johnson, R.L., Johmson, G.O., Nurmi, J.T., and Tratnyet, P.G., 2009, Natural organic matter enhanced mobility of nano zerovalent iron, Environ. Sci. Technol., 43, 5455-5460.10.1021/es900474f

[8] Kim, C., Ahn, J.Y., Ngoc, T.H., Kim, H.S., Jun, S.C., and Hwang, I., 2013, Characterization of the transport of zero-valent iron nanoparticles in an aquifer for application of reactive zone technology, J. Soil Groundw. Environ., 18(3), 109-118.10.7857/JSGE.2013.18.3.109

[9] Kim, H.S., Ahn, J.Y., Hwang, K.Y., Kim, I.K., and Hwang I., 2010, Atmospherically stable nanoscale zero-valent iron particles formed under controlled air contact: characterisitcs and reactivity, Environ. Sci. Technol., 44, 1760-1766.10.1021/es902772r

[10] Kim, H.S., Ahn, J.Y., Kim, C., Lee, S., and Hwang, I., 2014, Effect of anions and humic acid on the performance of nanoscale zero-valent iron particles coated with polyacryic acid, Chemosphere. 113, 93-100.10.1016/j.chemosphere.2014.04.047

[11] Kim, H.S., Kim, T., Ahn, J.Y., Hwang, K.Y., Park, J.Y., Lim, T.T., and Hwang I., 2012, Aging characteristics reactivity of two types of nanoscale zero-valent iron particles ($Fe^{BH}$ and $Fe^{H2}$) in nitrate reduction, Chem. Eng. J., 197, 16-23.10.1016/j.cej.2012.05.018

[12] Kim, T., Kim, H., Lee, J., Cheon, J., Lee, K., and Hwang, I., 2011, Effect of dissolved compounds in groundwater on TCE degradations reaction by nanoscale Zero-valent iron, Kor. Soc. Econ. Environ. Geol., 33(6), 413-419.

[13] Klimkova, S., Cernik, M., Lacinova, L., Filip, J., Jancik, D., and Zboril, R., 2011, Zero-valent iron nanoparticles in treatment of acid mine water from in situ uranium leaching, Chemosphere, 82(8), 1178-1184.10.1016/j.chemosphere.2010.11.075

[14] Korean Ministry of Environment, 2012, Operating report of groundwater monitoring system in 2011.

[15] MacDonald, J.A. and Kavanaugh, M.C., 1994, Restoring contaminated groundwater: an achievable goal?, Environ. Sci. Technol., 28(8), 362A-368A.

[16] Phenrat, T., Saleh, N., Sirk, K., Tilton, R.D., and Lowry, G.V., 2007, Aggregation and sedimentation of aqueous nanoscale zerovalent iron dispersions, Environ. Sci. Technol., 41(1), 284-290.10.1021/es061349a

[17] Quinn, J., Geiger, C., Clausen, C., O'hara, S., Krug, T., Major, D., Yoon, W.S., and Holdsworth, T., 2005, Field demonstration of DNAPL dehalogenation using emulsified zero-valent iron, Environ. Sci. Technol., 39, 1309-1318.10.1021/es0490018

[18] Saleh, N., Kim, H., Phenrat, T., Matyjaszewski, K., Tilton, R.D., and Lowry, G.V., 2008, Ionic strength and composition affect the mobility of surface-modified $Fe^0$ nanoparticles in water-saturated sand columns, Environ. Sci. Technol., 42(9), 3349-3355.10.1021/es071936b

[19] Saleh, N., Phenrat, T., Sirl, K., Dufour, B., Ok, J., Sarbu, T., Matyjaszewski, K., Tilton, R.D., and Lowry, G.V., 2005, Adsorbed triblock copolymers deliver reactive iron nanoparticles to the oil/water interface, Nano Lett., 5(12), 2489-2494.10.1021/nl0518268

[20] Sun, Y.P., Li, X.Q., Zhang, W.X. and Wang, H.P., 2007, A method for the preparation of stable dispersion of zero-valent iron nanoparticles, Colloids Surf., A, 308, 60-66.10.1016/j.colsurfa.2007.05.029

[21] Wei, Y., Wu, S., Chou, C., Che, C., Tsai, S., and Lien, H., 2010, Influence of nanoscale zero-valent iron on geochemical properties of groundwater and vinyl chloride degradation: A field case study, Water Res., 44(1), 131-140.10.1016/j.watres.2009.09.012

[22] Zhang, W., Quan, W., Wang, J., Zhang, Z., and Chen, S., 2006, Rapid and complete dechlorination of PCP in aqueous solution using Ni-Fe nanoparticles under assistance of ultrasound, Chemosphere, 65, 58-64.10.1016/j.chemosphere.2006.02.060

Journal of Soil and Groundwater Environment ISSN:1598-6438(Print) 2287-8831(Online) 지하수토양환경

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