Assessment of the Adsorption Capacity of Cadmium and Arsenic onto Paper Mill Sludge Using Batch Experiment

doi:10.7857/JSGE.2014.19.1.046

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2014 Vol.19, Issue 1 Preview Page Next Page

Assessment of the Adsorption Capacity of Cadmium and Arsenic onto Paper Mill Sludge Using Batch Experiment 회분식 실험을 통한 제지슬러지의 카드뮴 및 비소 흡착능 평가: 백종찬;여슬기;박준범;백종환;송영우;;;
Baek, Jongchan;Yeo, Seulki;Park, Junboum;Back, Jonghwan;Song, Youngwoo;Igarashi, T.;Tabelin, C.B.;

28 February 2014. pp. 46 ~ 53

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Abstract

The purpose of this study is to promote utilization of paper mill sludge as an adsorbent for stabilizing heavy metals in contaminated water by measuring the adsorption capacity of paper mill sludge for cadmium and arsenic. To measure adsorption capacity of paper mill sludge, sorption isotherm experiments were analyzed by Langmuir and Freundlich isotherm models. Also, two methods of chemical modifications were applied to improve the adsorption capacities of paper-mill-sludge: the first method used sodium hydroxide (NaOH), called PMS-1, and the second method used the NaOH and tartaric acid ($C_4H_6O_6$) together, called PMS-2. For Cd adsorption, PMS-1 presented the increase of reactivity while PMS-2 presented the decline of reactivity compared to that of untreated paper-mill-sludge. In case of As adsorption, both PMS-1 and PMS-2 showed the decrease of adsorption capacities. This is because zeta-potential of paper mill sludge was changed to more negative values during chemical modification process due to the hydroxyl group in NaOH and the carboxyl group in $C_4H_6O_6$, respectively. Therefore, we may conclude that the chemical treatment process increases adsorption capacity of paper mill sludge for cation heavy metals such as Cd but not for As.

Keywords

Paper mill sludge;Heavy metal adsorption;Zeta-potential variation;Chemical modification;

References

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Bismarck, A., Springer, J., Mohanty, A.K., Hinrichsen, G., and Khan, M.A., 2000, Characterization of several modified jute fibers using zeta-potential measurements, Colloid Polym. Sci., 278(3), 229-235.10.1007/s003960050036
Calace, N., Di Muro, A., Nardi, E., Petronio, B.M., and Pietroletti, M., 2002, Adsorption isotherms for describing heavy-metal retention in paper mill sludges, Ind. Eng. Chem. Res., 41(22), 5491-5497.10.1021/ie011029u
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Ju, S.Y., Yeon, I.J., Lee, M.H., Park, J.K., and Kim, K.Y., 2003, A study on the reusability of incinerated paper mill sludge ash as cement additive, Korean J. Sanitation, 18(2), 34-41.
Kim, E.H., Lee, S.S., Lee, G.H., Kim, Y.W., Park, J.B., and Oh, M.H., 2011, Assessment of the sorption characteristics of cadmium onto steel making slag in simulated sea water using batch experiment, J. of Korean Geotech. Soc., 27(4), 43-50.10.7843/kgs.2011.27.4.043
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Song, D.B., Bae, E.J., Kim, C.H., and Huh, M.R., 2010, Analysis of Plant Growth Effects Using Seedling Pots Made from Paper Mill Sludges, Korean J. Environ. Agric., 42(2), 12-19.
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Ministry of environment, 2012, Standard analytical methods for contamination in soils, Notification no. 2012-119 of the Ministry of environment
Park, K.H., Lee, C.H., Ryu, S.K., and Yang, X., 2007, Zetapotentials of oxygen and nitrogen enriched activated carbons for removal of copper ion, Carbon Letters, 8(4), 321-325.10.5714/CL.2007.8.4.321
Sciban, M., Klasnja, M., and Skrbi, B., 2006, Modified softwood sawdust as adsorbent of heavy metal ions from water, J. Hazard. Mater., 136, 266-271.10.1016/j.jhazmat.2005.12.009
Tabelin, C.B., Igarashi, T., Yoneda, T., and Tamamura, S., 2013, Utilization of natural and artificial adsorbents in the mitigation of arsenic leached from hydrothermally altered rock, Eng. Geol., 156, 58-67.10.1016/j.enggeo.2013.02.001
Weng, C.H. and Huang, C.P., 1994, Treatment of metal industrial waste water by fly ash and cement fixation, J. Environ. Eng., 120(6), 1470-1487.10.1061/(ASCE)0733-9372(1994)120:6(1470)
Wong, K.K., Lee, K.K., Low, K.S., and Haron, M.J., 2003, Removal of Cu and Pb by tartaric acid modified rice husk from aqueous solutions, Chemosphere, 50, 23-28.10.1016/S0045-6535(02)00598-2

Information

Publisher :The Korean Society of Soil and Groundwater Environment
Publisher(Ko) :한국지하수토양환경학회
Journal Title :Journal of Soil and Groundwater Environment
Journal Title(Ko) :지하수토양환경
Volume : 19
No :1
Pages :46 ~ 53
DOI :https://doi.org/10.7857/JSGE.2014.19.1.046

[1] Battaglia, A., Calace, N., Nardi, E., Petronio, B.M., and Pietroletti, M., 2003, Paper mill sludge-Soil mixture: Kinetic and thermodynamic tests of cadmium and lead sorption capability, Microchem. J., 75, 97-102.10.1016/S0026-265X(03)00074-2

[2] Bismarck, A., Springer, J., Mohanty, A.K., Hinrichsen, G., and Khan, M.A., 2000, Characterization of several modified jute fibers using zeta-potential measurements, Colloid Polym. Sci., 278(3), 229-235.10.1007/s003960050036

[3] Calace, N., Di Muro, A., Nardi, E., Petronio, B.M., and Pietroletti, M., 2002, Adsorption isotherms for describing heavy-metal retention in paper mill sludges, Ind. Eng. Chem. Res., 41(22), 5491-5497.10.1021/ie011029u

[4] Framework Act on Environmental Policy, 2009, Standard of groundwater quality, No. 10.

[5] Han, J.S., 1998, groundwater environment and contamination, pakyoungsa, 609-612.

[6] Harry, I.D., Saha, B., and Cumming, I.W., 2006, Effect of electrochemical oxidation of activated carbon fiber on competitive and noncompetitive sorption of trace toxic metal ions from aqueous solution, J. Colloid Interface Sci., 304(1), 9-20.10.1016/j.jcis.2006.08.012

[7] Ju, S.Y., Yeon, I.J., Lee, M.H., Park, J.K., and Kim, K.Y., 2003, A study on the reusability of incinerated paper mill sludge ash as cement additive, Korean J. Sanitation, 18(2), 34-41.

[8] Kim, E.H., Lee, S.S., Lee, G.H., Kim, Y.W., Park, J.B., and Oh, M.H., 2011, Assessment of the sorption characteristics of cadmium onto steel making slag in simulated sea water using batch experiment, J. of Korean Geotech. Soc., 27(4), 43-50.10.7843/kgs.2011.27.4.043

[9] Lee, H.Y., Jeon, C., Lim, K.J., Hong, K.C., Lim, J.E., Choi, B.S., Kim, N.W., Yang, J.E., and Ok, Y.S., 2009, Adsorption characteristics of heavy metal ions onto chemically modified rice husk and sawdust from aqueous solutions, Korean J. Environ. Agric., 28(2), 158-164.10.5338/KJEA.2009.28.2.158

[10] Song, D.B., Bae, E.J., Kim, C.H., and Huh, M.R., 2010, Analysis of Plant Growth Effects Using Seedling Pots Made from Paper Mill Sludges, Korean J. Environ. Agric., 42(2), 12-19.

[11] Lim, M.H., Lee, J.K., Nam, S.Y., and Ahn, J.H., 2011, Sustainable treatment process of paper making industry for paper sludge recycling technology, J. Kor. Ceram. Soc, 14(2), 7-14.

[12] Memona, S.Q., Memon, N., Shah, S.W., Khuhawar, M.Y., and Bhanger, M.I., 2007, Sawdust - A green and economical sorbent for the removal of cadmium (II) ions, J. Hazard. Mater., 139, 116-121.10.1016/j.jhazmat.2006.06.013

[13] Ministry of environment, 2011, Worrisome level of soil contamination, Soil environment conservation act enforcement rule, Notification no. 509 of the Ministry of environment.

[14] Ministry of environment, 2012, Standard analytical methods for contamination in soils, Notification no. 2012-119 of the Ministry of environment

[15] Park, K.H., Lee, C.H., Ryu, S.K., and Yang, X., 2007, Zetapotentials of oxygen and nitrogen enriched activated carbons for removal of copper ion, Carbon Letters, 8(4), 321-325.10.5714/CL.2007.8.4.321

[16] Sciban, M., Klasnja, M., and Skrbi, B., 2006, Modified softwood sawdust as adsorbent of heavy metal ions from water, J. Hazard. Mater., 136, 266-271.10.1016/j.jhazmat.2005.12.009

[17] Tabelin, C.B., Igarashi, T., Yoneda, T., and Tamamura, S., 2013, Utilization of natural and artificial adsorbents in the mitigation of arsenic leached from hydrothermally altered rock, Eng. Geol., 156, 58-67.10.1016/j.enggeo.2013.02.001

[18] Weng, C.H. and Huang, C.P., 1994, Treatment of metal industrial waste water by fly ash and cement fixation, J. Environ. Eng., 120(6), 1470-1487.10.1061/(ASCE)0733-9372(1994)120:6(1470)

[19] Wong, K.K., Lee, K.K., Low, K.S., and Haron, M.J., 2003, Removal of Cu and Pb by tartaric acid modified rice husk from aqueous solutions, Chemosphere, 50, 23-28.10.1016/S0045-6535(02)00598-2

Journal of Soil and Groundwater Environment ISSN:1598-6438(Print) 2287-8831(Online) 지하수토양환경

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