Oxidative Degradation of Phenol Using Zero-Valent Iron-Based Fenton-Like Systems

doi:10.7857/JSGE.2013.18.4.050

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2013 Vol.18, Issue 4 Preview Page

Oxidative Degradation of Phenol Using Zero-Valent Iron-Based Fenton-Like Systems 영가철 기반 펜톤 시스템을 활용한 페놀의 산화분해: 김학현;이혜진;김형은;이홍신;이병대;이창하;
Kim, Hak-Hyeon;Lee, Hye-Jin;Kim, Hyung-Eun;Lee, Hongshin;Lee, Byeong-Dae;Lee, Changha;

31 August 2013. pp. 50 ~ 57

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Abstract

For the last couple of decades, the Fenton (-like) systems have been extensively studied for oxidation of organic contaminants in water. Recently, zero-valent iron (ZVI) has received attention as a Fenton catalyst as well as a reducing agent capable of producing reactive oxidants from oxygen. In this study, the ZVI-based Fenton reaction was assessed for the oxidative degradation of phenol using $ZVI/O_2$, $ZVI/H_2O_2$, ZVI/Oxalate/$O_2$ and hv/ZVI/Oxalate/$O_2$ systems. Reaction parameters such as pH and reagent dose (e.g., ZVI, $H_2O_2$, and oxalate) were examined. In the presence of oxalate (ZVI/Oxalate/$O_2$ and hv/ZVI/Oxalate/$O_2$ systems), the degradation of phenol was greatly enhanced at neutral pH values. It was found that ZVI accelerates the Fenton reaction by reducing Fe(III) into Fe(II). The conversion of Fe(III) into Fe(II) by ZVI was more stimulated at acidic pH than at near-neutral pH values.

Keywords

Advanced oxidation process;Fenton reaction;Zero-valent iron;Hydroxyl radical;Phenol oxidation;

References

Agrawal, A. and Tratnyek, P.G., 1996, Reduction of nitro aromatic compounds by zero-valent iron metal, Environ. Sci. Technol., 30(1), 153-160.
Buxton, G.V., Greenstock, C.L., Helman, W.P., and Ross, A.B., 1988, Critical review of rate constants for reactions of hydrated electrons, hydrogen atoms and hydroxyl radicals in aqueous solution, J. Phys. Chem. Ref. Data, 17(2), 513-886.
Eisenberg, G., 1943, Colorimetric determination of hydrogen peroxide, Ind. Eng. Chem. Anal. Ed., 15(5), 327-328.
Hatchard, C.G. and Parker, C.A., 1956, A new sensitive chemical actinometer. II. Potassium ferrioxalate as a standard chemical actinometer, Proc. Roy. Soc. Lon. A, 235(1203), 518-536.10.1098/rspa.1956.0102
Jeong, J. and Yoon, J., 2005, pH effect on OH radical production in photo/ferrioxalate system, Water Res., 39(13), 2893-2900.10.1016/j.watres.2005.05.014
Joo, S.H., Feitz, A.J., and Waite, T.D., 2004, Oxidative degradation of the carbothioate herbicide, molinate, using nanoscale zero-valent iron, Environ. Sci. Technol., 38(7), 2242-2247.10.1021/es035157g
Keenan, C.R. and Sedlak, D.L., 2008a, Factors affecting the yield of oxidants from the reaction of nanoparticulate zerovalent iron and oxygen, Environ. Sci. Technol., 42(4), 1262-1267.10.1021/es7025664
Keenan, C.R. and Sedlak, D.L., 2008b, Ligand-enhanced reactive oxidant generation by nanoparticulate zero-valent iron and oxygen, Environ. Sci. Technol., 42(18), 6936-6941.10.1021/es801438f
Lee, C. and Sedlak, D.L., 2008, Enhanced formation of oxidants from bimetallic nickel-iron nanoparticles in the presence of oxygen, Environ. Sci. Technol., 42(22), 8528-8533.10.1021/es801947h
Lee, Y., Jeong, J., Lee, C., Kim, S., and Yoon, J., 2003, Influence of various reaction parameters on 2,4-D removal in photo/ferrioxalate/$H_{2}O_{2}$ process, Chemosphere, 51, 901-912.10.1016/S0045-6535(03)00044-4
Matheson, L.J. and Tratnyek, P.G., 1994, Reductive Dehalogenation of Chlorinated Methanes by Iron Metal, Environ. Sci. Technol., 28(12), 2045-2053.10.1021/es00061a012
Ministry of Environment, 2012, 2011 Annual groundwater quality monitoring report.
Nam, S., Renganathan, V., and Tratnyek, P.G., 2001, Substituent effects on azo dye oxidation by the Fe(III)-EDTA-$H_{2}O_{2}$ system, Chemosphere, 45(1), 59-65.10.1016/S0045-6535(00)00599-3
Pham, A.L., Lee, C., Doyle, F.M., and Sedlak, D.L., 2009, A silica-supported iron oxide catalyst capable of activating hydrogen peroxide at neutral pH values, Environ. Sci. Technol., 43(23), 8930-8935.10.1021/es902296k
Roberts, A.L., Totten, L.A., Arnold, W.A., Burris, D.R., and Campbell, T. J., 1996, Reductive elimination of chlorinated ethylenes by zero-valent metals, Environ. Sci. Technol., 30(8), 2654-2659.10.1021/es9509644
Roy, G., de Donato, P., Gorner, T., and Barres, O., 2003, Study of tropaeolin degradation by iron-proposition of a reaction mechanism, Water Res., 37(20), 4954-4964.10.1016/S0043-1354(03)00438-X
Ruangchainikom, C., Liao, C.-H., Anotai, J., and Lee, M.-T., 2006, Characteristics of nitrate reduction by zero-valent iron powder in the recirculated and $CO_{2}$-bubbled system, Water Res., 40(2), 195-204.10.1016/j.watres.2005.09.047
Safarzadeh-Amiri, A., Bolton, J.R., and Cater, S.R., 1997, Ferrioxalate-mediated photodegradation of organic pollutants in contaminated water, Water. Res., 31(4), 787-798.10.1016/S0043-1354(96)00373-9
Tamura, H., Goto, K., Yotsuyanagi, T., and Nagayama, M., 1974, Spectrophotometric determination of iron(II) with 1,10-phenanthroline in the presence of large amounts of iron(III), Talanta, 21(4), 314-318.10.1016/0039-9140(74)80012-3
Xue, X., Hanna, K., Despas, C., Wu, F., and Deng, N., 2009, Effect of chelating agent on the oxidation rate of PCP in the magnetite/$H_{2}O_{2}$ system at neutral pH, J. Mol. Cat. A-Chem., 311(1-2), 29-35.10.1016/j.molcata.2009.06.016
Zecevic, S., Drazic, D.M., and Gojkovic, S., 1989, Oxygen reduction on iron. Part III. An analysis of the rotating disk-ring electrode measurements in near neutral solutions, J. Electroanal. Chem., 265(1-2), 179-193.10.1016/0022-0728(89)80188-3
Zecevic, S., Drazic, D.M., and Gojkovic, S., 1991, Oxygen reduction on iron. Part IV. The reduction of hydrogen peroxide as the intermediate in oxygen reduction reaction in alkaline solutions, Electrochim. Acta, 36(1), 5-14.10.1016/0013-4686(91)85172-4
Zhou, T., Li, Y.Z., Ji, J., Wong, F.S., and Lu, X.H., 2008, Oxidation of 4-chlorophenol in a heterogeneous zero valent iron/$H_{2}O_{2}$ Fenton-like system: Kinetic, pathway and effect factors, Sep. Purif. Technol., 62(3), 551-558.10.1016/j.seppur.2008.03.008

Information

Publisher :The Korean Society of Soil and Groundwater Environment
Publisher(Ko) :한국지하수토양환경학회
Journal Title :Journal of Soil and Groundwater Environment
Journal Title(Ko) :지하수토양환경
Volume : 18
No :4
Pages :50 ~ 57
DOI :https://doi.org/10.7857/JSGE.2013.18.4.050

[1] Agrawal, A. and Tratnyek, P.G., 1996, Reduction of nitro aromatic compounds by zero-valent iron metal, Environ. Sci. Technol., 30(1), 153-160.

[2] Buxton, G.V., Greenstock, C.L., Helman, W.P., and Ross, A.B., 1988, Critical review of rate constants for reactions of hydrated electrons, hydrogen atoms and hydroxyl radicals in aqueous solution, J. Phys. Chem. Ref. Data, 17(2), 513-886.

[3] Eisenberg, G., 1943, Colorimetric determination of hydrogen peroxide, Ind. Eng. Chem. Anal. Ed., 15(5), 327-328.

[4] Hatchard, C.G. and Parker, C.A., 1956, A new sensitive chemical actinometer. II. Potassium ferrioxalate as a standard chemical actinometer, Proc. Roy. Soc. Lon. A, 235(1203), 518-536.10.1098/rspa.1956.0102

[5] Jeong, J. and Yoon, J., 2005, pH effect on OH radical production in photo/ferrioxalate system, Water Res., 39(13), 2893-2900.10.1016/j.watres.2005.05.014

[6] Joo, S.H., Feitz, A.J., and Waite, T.D., 2004, Oxidative degradation of the carbothioate herbicide, molinate, using nanoscale zero-valent iron, Environ. Sci. Technol., 38(7), 2242-2247.10.1021/es035157g

[7] Keenan, C.R. and Sedlak, D.L., 2008a, Factors affecting the yield of oxidants from the reaction of nanoparticulate zerovalent iron and oxygen, Environ. Sci. Technol., 42(4), 1262-1267.10.1021/es7025664

[8] Keenan, C.R. and Sedlak, D.L., 2008b, Ligand-enhanced reactive oxidant generation by nanoparticulate zero-valent iron and oxygen, Environ. Sci. Technol., 42(18), 6936-6941.10.1021/es801438f

[9] Lee, C. and Sedlak, D.L., 2008, Enhanced formation of oxidants from bimetallic nickel-iron nanoparticles in the presence of oxygen, Environ. Sci. Technol., 42(22), 8528-8533.10.1021/es801947h

[10] Lee, Y., Jeong, J., Lee, C., Kim, S., and Yoon, J., 2003, Influence of various reaction parameters on 2,4-D removal in photo/ferrioxalate/$H_{2}O_{2}$ process, Chemosphere, 51, 901-912.10.1016/S0045-6535(03)00044-4

[11] Matheson, L.J. and Tratnyek, P.G., 1994, Reductive Dehalogenation of Chlorinated Methanes by Iron Metal, Environ. Sci. Technol., 28(12), 2045-2053.10.1021/es00061a012

[12] Ministry of Environment, 2012, 2011 Annual groundwater quality monitoring report.

[13] Nam, S., Renganathan, V., and Tratnyek, P.G., 2001, Substituent effects on azo dye oxidation by the Fe(III)-EDTA-$H_{2}O_{2}$ system, Chemosphere, 45(1), 59-65.10.1016/S0045-6535(00)00599-3

[14] Pham, A.L., Lee, C., Doyle, F.M., and Sedlak, D.L., 2009, A silica-supported iron oxide catalyst capable of activating hydrogen peroxide at neutral pH values, Environ. Sci. Technol., 43(23), 8930-8935.10.1021/es902296k

[15] Roberts, A.L., Totten, L.A., Arnold, W.A., Burris, D.R., and Campbell, T. J., 1996, Reductive elimination of chlorinated ethylenes by zero-valent metals, Environ. Sci. Technol., 30(8), 2654-2659.10.1021/es9509644

[16] Roy, G., de Donato, P., Gorner, T., and Barres, O., 2003, Study of tropaeolin degradation by iron-proposition of a reaction mechanism, Water Res., 37(20), 4954-4964.10.1016/S0043-1354(03)00438-X

[17] Ruangchainikom, C., Liao, C.-H., Anotai, J., and Lee, M.-T., 2006, Characteristics of nitrate reduction by zero-valent iron powder in the recirculated and $CO_{2}$-bubbled system, Water Res., 40(2), 195-204.10.1016/j.watres.2005.09.047

[18] Safarzadeh-Amiri, A., Bolton, J.R., and Cater, S.R., 1997, Ferrioxalate-mediated photodegradation of organic pollutants in contaminated water, Water. Res., 31(4), 787-798.10.1016/S0043-1354(96)00373-9

[19] Tamura, H., Goto, K., Yotsuyanagi, T., and Nagayama, M., 1974, Spectrophotometric determination of iron(II) with 1,10-phenanthroline in the presence of large amounts of iron(III), Talanta, 21(4), 314-318.10.1016/0039-9140(74)80012-3

[20] Xue, X., Hanna, K., Despas, C., Wu, F., and Deng, N., 2009, Effect of chelating agent on the oxidation rate of PCP in the magnetite/$H_{2}O_{2}$ system at neutral pH, J. Mol. Cat. A-Chem., 311(1-2), 29-35.10.1016/j.molcata.2009.06.016

[21] Zecevic, S., Drazic, D.M., and Gojkovic, S., 1989, Oxygen reduction on iron. Part III. An analysis of the rotating disk-ring electrode measurements in near neutral solutions, J. Electroanal. Chem., 265(1-2), 179-193.10.1016/0022-0728(89)80188-3

[22] Zecevic, S., Drazic, D.M., and Gojkovic, S., 1991, Oxygen reduction on iron. Part IV. The reduction of hydrogen peroxide as the intermediate in oxygen reduction reaction in alkaline solutions, Electrochim. Acta, 36(1), 5-14.10.1016/0013-4686(91)85172-4

[23] Zhou, T., Li, Y.Z., Ji, J., Wong, F.S., and Lu, X.H., 2008, Oxidation of 4-chlorophenol in a heterogeneous zero valent iron/$H_{2}O_{2}$ Fenton-like system: Kinetic, pathway and effect factors, Sep. Purif. Technol., 62(3), 551-558.10.1016/j.seppur.2008.03.008

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