Characterization and Emission Sources of PAHs for Industrial Complex Soils in Jeollanamdo

doi:10.7857/JSGE.2016.21.3.049

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2016 Vol.21, Issue 3 Preview Page Next Page

Characterization and Emission Sources of PAHs for Industrial Complex Soils in Jeollanamdo 전라남도 산업단지 주변권역 토양의 PAHs 특성 및 발생원 분포: 박수호;이우범;김성욱;김종오;
Park, Soo-Ho;Lee, Woo-Bum;Kim, Sung-Ug;Kim, Jongo;

30 June 2016. pp. 49 ~ 57

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Abstract

This study investigated the 16 priority PAH concentrations and emission sources from two region (Southwest and East) soils in Jeollanamdo. National industrial complexes have been operated in these regions. PAH concentrations in east region were higher than southeast region, and 9.1 times higher for polluted area and approximately 8.5 times higher for industrial complex were observed. Individual PAH ratios and LMW/HMW ratio indicated that PAHs were emitted from pyrogenic sources in two regions. Average Ant/(Ant+Phe) ratios in southwest and east were 0.14 and 0.22, respectively. From a principal component analysis, it was concluded that PAHs were originated from vehicles and coal power plants.

Keywords

Industrial complex;PAHs;Pyrogenic;Principal component analysis;Soil;

References

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Guo, H., Lee, S.C., Ho, K.F., Wang, X.M., and Zou, S.C., 2003, Particle-associated polycyclic aromatic hydrocarbons in urban air of Hong Kong, Atmos. Environ. 37(38), 5307-5317.10.1016/j.atmosenv.2003.09.011
Harrison R.M., Smith, D.J.T., and Luhana, L., 1996, Source apportionment of atmospheric polycyclic aromatic hydrocarbons collected from an urban location in Birmingham, U.K. Environ. Sci. Technol., 30(3), 825-832.10.1021/es950252d
International Agency for Research on Cancer (IARC), 1987, IARC Monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Humans, IARC, Lyons, Suppl. 7.
Juan C.C., Emillen P., Charles B., Michel K., and Jose A.C., 1989, Determination of hydrocarbon sources using n-alkane and polyaromatic hydrocarbon distribution indexes. Case study: Rio de la plata estuary, Argentina, Environ. Sci. Technol., 23, 888-894.10.1021/es00065a019
Kang, J., Kim, G.B., and Lee, C.-B., 2004, Atmospheric particulate polycyclic aromatic hydrocarbons in the East sea : Relation to air mass trajectory, J. of the Korean Society for Environmental Analysis, 7(2), 53-60.
Khalili, N.R., Scheff, P.A., and Holsen, T.M., 1995, PAH source fingerprints for coke ovens, diesel and gasoline-engines, highway tunnels, and wood combustion emissions, Atmos. Environ. 29, 533-542.10.1016/1352-2310(94)00275-P
Kim, D. H., 2000, Concentration levels and distribution characteristics of polycyclic aromatic hydrocarbons in soil in Seoul, Master's Thesis, Hanyang University.
Kim, K.Y., Kim, U.-J. Kim, Jung, T.-U. Jung, Choi, S.-D. Choi and Oh, J., 2015, Distribution characteristics of PAHs in the multimedia of the terrestrial environmental in Busan, J. of the Korean Society for Environmental Analysis, 18(2), 121-130.
Mari, M., Harrison, R.M., Schuhmacher, M., Domingo, J.L., and Pongpiachan, S., 2010, Inferences over the sources and processes affecting polycyclic aromatic hydrocarbons in the atmosphere derived from measured data, Science of the Total. Environment, 408, 2387-2393.10.1016/j.scitotenv.2010.01.054
Ministry of Environment, 2012, 2012 Soil survey network and soil pollution investigation.
Ministry of Food and Drug Safety, 2010, Polycyclic aromatic hydrocarbons.
Nam, J.J., Song, B.H., Eom, K.C., Lee, S.H., and Smith, A., 2003, Distribution of polycyclic aromatic hydrocarbons in agricultural soils in South Korea, Chemosphere, 50, 1281-1289.10.1016/S0045-6535(02)00764-6
Ray, S., Khillare, P.S., Agarwal, T., and Shridhar, V., 2008, Assessment of PAHs in soil around the international airport in Delhi, India, J. Hard. Mater., 156, 9-16.10.1016/j.jhazmat.2007.11.099
Simcik, M.F., Eisenreich, S.J., and Lioy, P.J., 1999, Source apportionment and source/sink relationships of PAHs in the coastal atmosphere of Chicago and Lake Michigan, Atmos. Environ. 33, 5071-5079.10.1016/S1352-2310(99)00233-2
Sofowote, U.M., McCarry, B.E., and Marvin, C.H., 2008, Source apportionment of PAH in Hamilton Harbour suspended sediments: comparison of two factor analysis methods, Environ. Sci. Technol. 42(16), 6007-6014.10.1021/es800219z
US EPA, 2015, http://www.epa.gov/iris/.
Wang, X.-T., Miao, Y., Zhang, Y., Li, Y.-C., Wu, M.-H., and Yu, G., 2013, Polycyclic aromatic hydrocarbons (PAHs) in urban soils of the megacity Shanghai: Occurrence, source apportionment and potential human health risk, Sci. Total. Environ., 447, 80-89.10.1016/j.scitotenv.2012.12.086
Wilcke, W., 2007, Global patterns of polycyclic aromatic hydrocarbons (PAHs) in soil, Geoderma, 141(3-4), 157-166.10.1016/j.geoderma.2007.07.007
Xu, J., Guo, J.-Y., Liu, G.-R., Shi, G.-L., Guo, C.-S., Zhang, Y., and Feng, Y.-C., 2014, Historical trends of concentrations, source contributions and toxicities for PAHs in dated sediment cores from five lakes in western China, Sci. Total. Environ., 470-471, 519-526.10.1016/j.scitotenv.2013.10.022
Yang, S.Y.N., Connel, D.W., Hawarker, D.W., and S.I. Kayal, S.I., 1991, Polycyclic aromatic hydrocarbons in air, soil and vegetation in the vicinity of an urban roadway, Sci. Total. Environ., 102, 229-240.10.1016/0048-9697(91)90317-8
Yunker, M.B., Macdonald, R.W., Vingarzan, R., Mitchell, R.H., Goyette, D., and Sylvestre, S., 2002, PAHs in the Fraser River basin: a critical appraisal of PAH ratios as indicators of PAH source and composition, Org. Geochem., 33, 489-515.10.1016/S0146-6380(02)00002-5
Zhang, Y., Guo, C.S., Xu, J., Tian, Y.Z., Shi, G.L., and Feng, Y.C., 2012, Potential source contributions and risk assessment of PAHs in sediments form Taihu Lake, China: comparison of three receptor models, Water Res., 46(9), 3065-3073.10.1016/j.watres.2012.03.006
Zuo, Q., Duan, Y.H., Yang, Y., Wang, X.J., and Tao, S., 2007, Source apportionment of polycyclic aromatic hydrocarbons in surface soil in Tianjin, China, Environ. Pollut., 147(2), 303-310.10.1016/j.envpol.2006.05.029

Information

Publisher :The Korean Society of Soil and Groundwater Environment
Publisher(Ko) :한국지하수토양환경학회
Journal Title :Journal of Soil and Groundwater Environment
Journal Title(Ko) :지하수토양환경
Volume : 21
No :3
Pages :49 ~ 57
DOI :https://doi.org/10.7857/JSGE.2016.21.3.049

[1] Bucheli, T.D., Blum, F., Desaules, A., and Gustafsson, Ö., 2004, Polycyclic aromatic hydrocarbons, black carbon, and molecular markers in soils of Switzerland, Chemosphere, 56, 1061-1076.10.1016/j.chemosphere.2004.06.002

[2] Guo, H., Lee, S.C., Ho, K.F., Wang, X.M., and Zou, S.C., 2003, Particle-associated polycyclic aromatic hydrocarbons in urban air of Hong Kong, Atmos. Environ. 37(38), 5307-5317.10.1016/j.atmosenv.2003.09.011

[3] Harrison R.M., Smith, D.J.T., and Luhana, L., 1996, Source apportionment of atmospheric polycyclic aromatic hydrocarbons collected from an urban location in Birmingham, U.K. Environ. Sci. Technol., 30(3), 825-832.10.1021/es950252d

[4] International Agency for Research on Cancer (IARC), 1987, IARC Monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Humans, IARC, Lyons, Suppl. 7.

[5] Juan C.C., Emillen P., Charles B., Michel K., and Jose A.C., 1989, Determination of hydrocarbon sources using n-alkane and polyaromatic hydrocarbon distribution indexes. Case study: Rio de la plata estuary, Argentina, Environ. Sci. Technol., 23, 888-894.10.1021/es00065a019

[6] Kang, J., Kim, G.B., and Lee, C.-B., 2004, Atmospheric particulate polycyclic aromatic hydrocarbons in the East sea : Relation to air mass trajectory, J. of the Korean Society for Environmental Analysis, 7(2), 53-60.

[7] Khalili, N.R., Scheff, P.A., and Holsen, T.M., 1995, PAH source fingerprints for coke ovens, diesel and gasoline-engines, highway tunnels, and wood combustion emissions, Atmos. Environ. 29, 533-542.10.1016/1352-2310(94)00275-P

[8] Kim, D. H., 2000, Concentration levels and distribution characteristics of polycyclic aromatic hydrocarbons in soil in Seoul, Master's Thesis, Hanyang University.

[9] Kim, K.Y., Kim, U.-J. Kim, Jung, T.-U. Jung, Choi, S.-D. Choi and Oh, J., 2015, Distribution characteristics of PAHs in the multimedia of the terrestrial environmental in Busan, J. of the Korean Society for Environmental Analysis, 18(2), 121-130.

[10] Mari, M., Harrison, R.M., Schuhmacher, M., Domingo, J.L., and Pongpiachan, S., 2010, Inferences over the sources and processes affecting polycyclic aromatic hydrocarbons in the atmosphere derived from measured data, Science of the Total. Environment, 408, 2387-2393.10.1016/j.scitotenv.2010.01.054

[11] Ministry of Environment, 2012, 2012 Soil survey network and soil pollution investigation.

[12] Ministry of Food and Drug Safety, 2010, Polycyclic aromatic hydrocarbons.

[13] Nam, J.J., Song, B.H., Eom, K.C., Lee, S.H., and Smith, A., 2003, Distribution of polycyclic aromatic hydrocarbons in agricultural soils in South Korea, Chemosphere, 50, 1281-1289.10.1016/S0045-6535(02)00764-6

[14] Ray, S., Khillare, P.S., Agarwal, T., and Shridhar, V., 2008, Assessment of PAHs in soil around the international airport in Delhi, India, J. Hard. Mater., 156, 9-16.10.1016/j.jhazmat.2007.11.099

[15] Simcik, M.F., Eisenreich, S.J., and Lioy, P.J., 1999, Source apportionment and source/sink relationships of PAHs in the coastal atmosphere of Chicago and Lake Michigan, Atmos. Environ. 33, 5071-5079.10.1016/S1352-2310(99)00233-2

[16] Sofowote, U.M., McCarry, B.E., and Marvin, C.H., 2008, Source apportionment of PAH in Hamilton Harbour suspended sediments: comparison of two factor analysis methods, Environ. Sci. Technol. 42(16), 6007-6014.10.1021/es800219z

[17] US EPA, 2015, http://www.epa.gov/iris/.

[18] Wang, X.-T., Miao, Y., Zhang, Y., Li, Y.-C., Wu, M.-H., and Yu, G., 2013, Polycyclic aromatic hydrocarbons (PAHs) in urban soils of the megacity Shanghai: Occurrence, source apportionment and potential human health risk, Sci. Total. Environ., 447, 80-89.10.1016/j.scitotenv.2012.12.086

[19] Wilcke, W., 2007, Global patterns of polycyclic aromatic hydrocarbons (PAHs) in soil, Geoderma, 141(3-4), 157-166.10.1016/j.geoderma.2007.07.007

[20] Xu, J., Guo, J.-Y., Liu, G.-R., Shi, G.-L., Guo, C.-S., Zhang, Y., and Feng, Y.-C., 2014, Historical trends of concentrations, source contributions and toxicities for PAHs in dated sediment cores from five lakes in western China, Sci. Total. Environ., 470-471, 519-526.10.1016/j.scitotenv.2013.10.022

[21] Yang, S.Y.N., Connel, D.W., Hawarker, D.W., and S.I. Kayal, S.I., 1991, Polycyclic aromatic hydrocarbons in air, soil and vegetation in the vicinity of an urban roadway, Sci. Total. Environ., 102, 229-240.10.1016/0048-9697(91)90317-8

[22] Yunker, M.B., Macdonald, R.W., Vingarzan, R., Mitchell, R.H., Goyette, D., and Sylvestre, S., 2002, PAHs in the Fraser River basin: a critical appraisal of PAH ratios as indicators of PAH source and composition, Org. Geochem., 33, 489-515.10.1016/S0146-6380(02)00002-5

[23] Zhang, Y., Guo, C.S., Xu, J., Tian, Y.Z., Shi, G.L., and Feng, Y.C., 2012, Potential source contributions and risk assessment of PAHs in sediments form Taihu Lake, China: comparison of three receptor models, Water Res., 46(9), 3065-3073.10.1016/j.watres.2012.03.006

[24] Zuo, Q., Duan, Y.H., Yang, Y., Wang, X.J., and Tao, S., 2007, Source apportionment of polycyclic aromatic hydrocarbons in surface soil in Tianjin, China, Environ. Pollut., 147(2), 303-310.10.1016/j.envpol.2006.05.029

Journal of Soil and Groundwater Environment ISSN:1598-6438(Print) 2287-8831(Online) 지하수토양환경

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