Cu and Cd Sorption of the Biochar Derived from Coffee Sludge

doi:10.7857/JSGE.2012.17.2.047

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2012 Vol.17, Issue 2 Preview Page Next Page

Cu and Cd Sorption of the Biochar Derived from Coffee Sludge 커피 슬러지 바이오차의 Cu와 Cd 흡착제거 특성 연구: 김병문;강창환;양재규;나정균;정종암;정형진;임진환;고경민;김완희;장윤영;
Kim, Byung-Moon;Kang, Chang-Hwan;Yang, Jae-Kyu;Na, Jung-Kyun;Jung, Jong-Am;Jung, Hyung-Jin;Lim, Jin-Hwan;Ko, Kyung-Min;Kim, Wan-Hee;Chang, Yoon-Young;

30 April 2012. pp. 47 ~ 53

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Abstract

In this study, the adsorption of $Cu^{2+}$ and $Cd^{2+}$ from aqueous solution on the biochar derived from used coffee grounds at different pyrolysis temperatures has been investigated as a potential low-cost treatment method for heavy metal-containing waters. Three biochar samples prepared by heating coffee sludge at temperature of $300^{\circ}C$ (B300), $500^{\circ}C$ (B500), and $700^{\circ}C$ (B700) were tested for the adsorption capacity and kinetics of Cd and Cu. Also the influencing factor of heavy metal removal by ion exchange in terms of cation exchange capacity (CEC) of each biochar was measured. Adsorption of Ca and Cu by biochar produced at higher pyrolysis temperature showed higher adsorption capacity but the optimal pyrolysis temperature based on performance and economy was known as $500^{\circ}C$. Sorption of Cu and Cd by biochar followed a Langmuir model at pH 6~6.5, attributing mainly to surface sorption. The biochar was more effective in Cu and Cd sorption than activated carbon (AC), with BC 500 being the most effective, which indicates that sorption of Cd and Cu by coffee sludge biochar is partly influenced by chemical sorption on surface functional group as well as physical sorption.

Keywords

Pyrolysis;Biochar;Sorbent;Metal;Coffee sludge;

References

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이수민, 2011, 목재를 이용한 새로운 유전(油田) 개발, 임업정보, p. 88-92.
Aristidis, N.A. and Kallirroy-Ioanna, G.I., 2010, Development of a sequential injection dispersive liquid-liquid microextraction system for electrothermal atomic absorption spectrometry by using a hydrophobic sorbent material: Determination of lead and cadmium in natural waters, Analytica Chimica Acta, 668, 35-40.10.1016/j.aca.2009.10.063
Cao, X., Ma, L., Gao B., and Willie H., 2009, Dairy-Manure Derived Biochar Effectively Sorbs Lead and Atrazine, Environ. Sci. Technol, 43, 3285-3291.10.1021/es803092k
Dinesh, M., Charles, U.P.Jr, Mark. B., Fran, S., Ben, Y., Javeed, M., Philip, H.S., Maria, F.A.-F., Vicente, G.-S., and Henry, G., 2007, Sorption of arsenic, cadmium, and lead by chars produced from fast pyrolysis of wood and bark during bio-oil production, J. Colloid and Interface Science, 310, 57-73.10.1016/j.jcis.2007.01.020
Ednilton, M.G., Adriana, da S., and Valfredo, A.L., 2006, Pre-concentration system for cadmium and lead determination in environmental samples using polyurethane foam/Me-BTANC, J. Hazardous Materials, B136, 757-762.
Fabio, K., Fabio, F.S., Rubia, K., Alexandre, L.S., and Pedro, V.O., 2008, Biomonitoring method for the simultaneous determination of cadmium and lead in whole blood by electrothermal atomic absorption spectrometry for assessment of environmental exposure, Talanta, 75, 246-252.10.1016/j.talanta.2007.11.003
Laird, D.A., Brown, R.C, Amonette, J.E., and Lehmann. J., 2009, Review of the pyrolysis platform for coproducing bio-oil and biochar, Biofuel. Bioprod. Bior, 3, 547-562.10.1002/bbb.169
Lehmann, J. and Joseph, S., 2009, Biochar for environmental management: science and technology. London: Earthscan, Ltd.
Lu, H., Zhang, W., Yang, Y., Huang, X., and Wang, S.R.Q., 2012, Relative distribution of $Pb^{2+}$ sorption mechanisms by sludge-derived biochar, Water Research, 46, 854-862.10.1016/j.watres.2011.11.058
Luke, B. and Marta, M., 2011, The immobilisation and retention of soluble arsenic, cadmium and zinc by biochar, Environmental Pollution, 159, 474-480.10.1016/j.envpol.2010.10.016
Minori, U., Isabel, M.L., Thomas, K.K., Chang, S., Lynda, H.W., and James E.R., 2010, Immobilization of Heavy Metal Ions ($Cu^{II},\;Cd^{II},\;Ni^{II},\;and\;Pb^{II}$) by Broiler Litter-Derived Biochars in Water and Soil, J. Agric. Food Chem., 58, 5538-5544.10.1021/jf9044217
Shahryar, A., Kobra, K., and Freshteh, A., 2011, Simultaneous determination of ultra trace amounts of lead and cadmium in food samples by adsorptive stripping voltammetry. Food Chemistry, 128, 254-257.10.1016/j.foodchem.2011.02.067
Zheng, W., Guo, M., Chow, T., Bennett, D.N., and Rajagopalan, N., 2010, Sorption properties of green waste biochar for two triazine pesticides, J. Hazardous Materials, 181, 121-126.10.1016/j.jhazmat.2010.04.103

Information

Publisher :The Korean Society of Soil and Groundwater Environment
Publisher(Ko) :한국지하수토양환경학회
Journal Title :Journal of Soil and Groundwater Environment
Journal Title(Ko) :지하수토양환경
Volume : 17
No :2
Pages :47 ~ 53
DOI :https://doi.org/10.7857/JSGE.2012.17.2.047

[1] 김정대, 2008, 목질계 바이오매스 에너지화를 위한 처리기술 및 방안 검토, 유기성자원학회 학술발표대회논문집, 유기성자원학회, p. 97-111.

[2] 이수민, 2011, 목재를 이용한 새로운 유전(油田) 개발, 임업정보, p. 88-92.

[3] Aristidis, N.A. and Kallirroy-Ioanna, G.I., 2010, Development of a sequential injection dispersive liquid-liquid microextraction system for electrothermal atomic absorption spectrometry by using a hydrophobic sorbent material: Determination of lead and cadmium in natural waters, Analytica Chimica Acta, 668, 35-40.10.1016/j.aca.2009.10.063

[4] Cao, X., Ma, L., Gao B., and Willie H., 2009, Dairy-Manure Derived Biochar Effectively Sorbs Lead and Atrazine, Environ. Sci. Technol, 43, 3285-3291.10.1021/es803092k

[5] Dinesh, M., Charles, U.P.Jr, Mark. B., Fran, S., Ben, Y., Javeed, M., Philip, H.S., Maria, F.A.-F., Vicente, G.-S., and Henry, G., 2007, Sorption of arsenic, cadmium, and lead by chars produced from fast pyrolysis of wood and bark during bio-oil production, J. Colloid and Interface Science, 310, 57-73.10.1016/j.jcis.2007.01.020

[6] Ednilton, M.G., Adriana, da S., and Valfredo, A.L., 2006, Pre-concentration system for cadmium and lead determination in environmental samples using polyurethane foam/Me-BTANC, J. Hazardous Materials, B136, 757-762.

[7] Fabio, K., Fabio, F.S., Rubia, K., Alexandre, L.S., and Pedro, V.O., 2008, Biomonitoring method for the simultaneous determination of cadmium and lead in whole blood by electrothermal atomic absorption spectrometry for assessment of environmental exposure, Talanta, 75, 246-252.10.1016/j.talanta.2007.11.003

[8] Laird, D.A., Brown, R.C, Amonette, J.E., and Lehmann. J., 2009, Review of the pyrolysis platform for coproducing bio-oil and biochar, Biofuel. Bioprod. Bior, 3, 547-562.10.1002/bbb.169

[9] Lehmann, J. and Joseph, S., 2009, Biochar for environmental management: science and technology. London: Earthscan, Ltd.

[10] Lu, H., Zhang, W., Yang, Y., Huang, X., and Wang, S.R.Q., 2012, Relative distribution of $Pb^{2+}$ sorption mechanisms by sludge-derived biochar, Water Research, 46, 854-862.10.1016/j.watres.2011.11.058

[11] Luke, B. and Marta, M., 2011, The immobilisation and retention of soluble arsenic, cadmium and zinc by biochar, Environmental Pollution, 159, 474-480.10.1016/j.envpol.2010.10.016

[12] Minori, U., Isabel, M.L., Thomas, K.K., Chang, S., Lynda, H.W., and James E.R., 2010, Immobilization of Heavy Metal Ions ($Cu^{II},\;Cd^{II},\;Ni^{II},\;and\;Pb^{II}$) by Broiler Litter-Derived Biochars in Water and Soil, J. Agric. Food Chem., 58, 5538-5544.10.1021/jf9044217

[13] Shahryar, A., Kobra, K., and Freshteh, A., 2011, Simultaneous determination of ultra trace amounts of lead and cadmium in food samples by adsorptive stripping voltammetry. Food Chemistry, 128, 254-257.10.1016/j.foodchem.2011.02.067

[14] Zheng, W., Guo, M., Chow, T., Bennett, D.N., and Rajagopalan, N., 2010, Sorption properties of green waste biochar for two triazine pesticides, J. Hazardous Materials, 181, 121-126.10.1016/j.jhazmat.2010.04.103

Journal of Soil and Groundwater Environment ISSN:1598-6438(Print) 2287-8831(Online) 지하수토양환경

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